Abstract
The activity for oxidative methanol reforming (OMR) as a function of time-on-stream was determined for CuO catalysts supported on ZnO or ZrO2. The ZnO-supported samples deactivated more quickly than the ZrO2-supported samples during 18 hour reactions at 225 °C. X-ray diffraction characterization showed that copper oxide particle size increases during the reaction, which implied that loss of CuO surface area is a cause of deactivation. The data suggested that the increase in CuO particle size was accompanied by sintering of the support, which was facilitated by the presence of water vapor at elevated temperatures.
| Original language | English |
|---|---|
| Pages (from-to) | 229-235 |
| Number of pages | 7 |
| Journal | Studies in Surface Science and Catalysis |
| Volume | 139 |
| Publication status | Published - 2001 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Catalysis
Cite this
Deactivation of CuO/ZnO and CuO/ZrO2 catalysts for oxidative methanol reforming. / Schrum, E. D.; Reitz, T. L.; Kung, Harold H.
In: Studies in Surface Science and Catalysis, Vol. 139, 2001, p. 229-235.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Deactivation of CuO/ZnO and CuO/ZrO2 catalysts for oxidative methanol reforming
AU - Schrum, E. D.
AU - Reitz, T. L.
AU - Kung, Harold H
PY - 2001
Y1 - 2001
N2 - The activity for oxidative methanol reforming (OMR) as a function of time-on-stream was determined for CuO catalysts supported on ZnO or ZrO2. The ZnO-supported samples deactivated more quickly than the ZrO2-supported samples during 18 hour reactions at 225 °C. X-ray diffraction characterization showed that copper oxide particle size increases during the reaction, which implied that loss of CuO surface area is a cause of deactivation. The data suggested that the increase in CuO particle size was accompanied by sintering of the support, which was facilitated by the presence of water vapor at elevated temperatures.
AB - The activity for oxidative methanol reforming (OMR) as a function of time-on-stream was determined for CuO catalysts supported on ZnO or ZrO2. The ZnO-supported samples deactivated more quickly than the ZrO2-supported samples during 18 hour reactions at 225 °C. X-ray diffraction characterization showed that copper oxide particle size increases during the reaction, which implied that loss of CuO surface area is a cause of deactivation. The data suggested that the increase in CuO particle size was accompanied by sintering of the support, which was facilitated by the presence of water vapor at elevated temperatures.
UR - http://www.scopus.com/inward/record.url?scp=0035786923&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035786923&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0035786923
VL - 139
SP - 229
EP - 235
JO - Studies in Surface Science and Catalysis
JF - Studies in Surface Science and Catalysis
SN - 0167-2991
ER -