Decoration of Inorganic Nanostructures by Metallic Nanoparticles to Induce Fluorescence, Enhance Solubility, and Tune Band Gap

Priyadarshi Ranjan, Sreejith Shankar, Ronit Popovitz-Biro, Sidney R. Cohen, Ifat Kaplan-Ashiri, Tali Dadosh, Linda J.W. Shimon, Bojana Višić, Reshef Tenne, Michal Lahav, Milko E. Van Der Boom

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

We report here a unique and efficient methodology for the surface functionalization of closed-cage inorganic fullerene-like (IF) nanoparticles and inorganic nanotubes (INTs) composed of two-dimensional nanomaterials of transition-metal chalcogenides (MS2; M = W or Mo). The first step is the physical coverage of these robust inorganic materials with monodispersed and dense monolayers of gold, silver, and palladium nanoparticles. The structural continuity at the interface between the IF/INT and the metallic nanoparticles is investigated. Lattice matching between these nanocrystalline materials and strong chemical affinity lead to efficient binding of the metallic nanoparticles onto the outer sulfide layer of the MS2-based structures. It is shown that this functionalization results in narrowing of the IF/INT optical band gap, increased work function, and improved surface-enhanced Raman scattering. In the second step, functionalization of the surface-bound nanoparticles is carried out by a ligand-exchange reaction. This ligand exchange involving the tetraoctylammonium bromide capping layer and an alkyl thiol enhances the solubility (∼10×) of the otherwise nearly insoluble materials in organic solvents. The scope of this method is further demonstrated by introducing a ruthenium(II) polypyridyl complex on the surface of the surface-bound AuNPs to generate fluorescent multicomponent materials.

Original languageEnglish
Pages (from-to)6748-6759
Number of pages12
JournalJournal of Physical Chemistry C
Volume122
Issue number12
DOIs
Publication statusPublished - Mar 29 2018

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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    Ranjan, P., Shankar, S., Popovitz-Biro, R., Cohen, S. R., Kaplan-Ashiri, I., Dadosh, T., Shimon, L. J. W., Višić, B., Tenne, R., Lahav, M., & Van Der Boom, M. E. (2018). Decoration of Inorganic Nanostructures by Metallic Nanoparticles to Induce Fluorescence, Enhance Solubility, and Tune Band Gap. Journal of Physical Chemistry C, 122(12), 6748-6759. https://doi.org/10.1021/acs.jpcc.8b00510