Abstract
Recent point defect formation and defect diffusion data in magnetite are used to analyze tracer diffusion data of Fe, Co, Cr and Al for motion enthalpies in vacancy and interstitial(cy) mechanisms. Correlations are made with ion properties such as radius, polarizability, and bond strength. The best correlation was made with the melting points of the end member ferrites containing the ions of interest. An explanation for the consistent minimum in diffusion coefficients is given.
| Original language | English |
|---|---|
| Pages (from-to) | 59-66 |
| Number of pages | 8 |
| Journal | Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics |
| Volume | 91 |
| Issue number | 1 |
| Publication status | Published - Jan 1987 |
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ASJC Scopus subject areas
- Chemical Engineering(all)
Cite this
DEFECTS AND CATION DIFFUSION IN MAGNETITE (VIII) : MIGRATION ENTHALPIES FOR IRON AND IMPURITY CATIONS. / Dieckmann, R.; Hilton, M. R.; Mason, Thomas O.
In: Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, Vol. 91, No. 1, 01.1987, p. 59-66.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - DEFECTS AND CATION DIFFUSION IN MAGNETITE (VIII)
T2 - MIGRATION ENTHALPIES FOR IRON AND IMPURITY CATIONS.
AU - Dieckmann, R.
AU - Hilton, M. R.
AU - Mason, Thomas O
PY - 1987/1
Y1 - 1987/1
N2 - Recent point defect formation and defect diffusion data in magnetite are used to analyze tracer diffusion data of Fe, Co, Cr and Al for motion enthalpies in vacancy and interstitial(cy) mechanisms. Correlations are made with ion properties such as radius, polarizability, and bond strength. The best correlation was made with the melting points of the end member ferrites containing the ions of interest. An explanation for the consistent minimum in diffusion coefficients is given.
AB - Recent point defect formation and defect diffusion data in magnetite are used to analyze tracer diffusion data of Fe, Co, Cr and Al for motion enthalpies in vacancy and interstitial(cy) mechanisms. Correlations are made with ion properties such as radius, polarizability, and bond strength. The best correlation was made with the melting points of the end member ferrites containing the ions of interest. An explanation for the consistent minimum in diffusion coefficients is given.
UR - http://www.scopus.com/inward/record.url?scp=0023120227&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0023120227&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0023120227
VL - 91
SP - 59
EP - 66
JO - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
JF - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
SN - 0005-9021
IS - 1
ER -