Dependence of optical lifetime on thermal transitions in some tetraalkylammonium tetrahalometalates

Nathan Presser; Mark A Ratner; Benson Ross Sundheim

doi:10.1016/0009-2614(77)80092-4

Dependence of optical lifetime on thermal transitions in some tetraalkylammonium tetrahalometalates

Nathan Presser, Mark A Ratner, Benson Ross Sundheim

Northwestern University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Abrupt peaks in the graphs of phosphorescence lifetime versus temperature were observed in solid (Bu₄N⁺)₂MnBr^2-₄ at temperatures at which thermal transitions were also observed. The corresponding MnCl^2-₄ system displayed a completely different behavior. The results are interpreted as reflecting changes in the rates of the radiationless decays, in turn reflecting the impediment of noncentrosymmetric vibrations.

Original language	English
Pages (from-to)	572-574
Number of pages	3
Journal	Chemical Physics Letters
Volume	45
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(77)80092-4
Publication status	Published - Feb 1 1977

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Condensed Matter Physics
Atomic and Molecular Physics, and Optics
Surfaces and Interfaces

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title = "Dependence of optical lifetime on thermal transitions in some tetraalkylammonium tetrahalometalates",

abstract = "Abrupt peaks in the graphs of phosphorescence lifetime versus temperature were observed in solid (Bu4N+)2MnBr2-4 at temperatures at which thermal transitions were also observed. The corresponding MnCl2-4 system displayed a completely different behavior. The results are interpreted as reflecting changes in the rates of the radiationless decays, in turn reflecting the impediment of noncentrosymmetric vibrations.",

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AU - Sundheim, Benson Ross

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N2 - Abrupt peaks in the graphs of phosphorescence lifetime versus temperature were observed in solid (Bu4N+)2MnBr2-4 at temperatures at which thermal transitions were also observed. The corresponding MnCl2-4 system displayed a completely different behavior. The results are interpreted as reflecting changes in the rates of the radiationless decays, in turn reflecting the impediment of noncentrosymmetric vibrations.

AB - Abrupt peaks in the graphs of phosphorescence lifetime versus temperature were observed in solid (Bu4N+)2MnBr2-4 at temperatures at which thermal transitions were also observed. The corresponding MnCl2-4 system displayed a completely different behavior. The results are interpreted as reflecting changes in the rates of the radiationless decays, in turn reflecting the impediment of noncentrosymmetric vibrations.

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