Abstract
There is great current interest in developing molecule-based electro-optic (EO) materials for opto-electronic and photonic technologies such as high-speed optical communications, integrated optics, and optical data processing and storage. Here we present the design rationale, synthesis, and molecular properties of two new organic chromophore classes enabling very large EO response along with new methodologies for self-assembling them in a non-centrosymmetric fashion. In the first class, we demonstrate that disruption of the π-conjugation via a sterically-induced molecular twisting results in unusual molecular characteristics and unprecedented hyperpolarizabilities (μβ values as high as -488,000 × 10-48 esu at 1907 nm). Guest-host poled polymers containing π-twisted chromophores exhibit very large electro-optic coefficients (r33) up to 320 pm/V at 1310 nm. Molecules of the second class enable the fabrication of acentric, high-quality, transparent, micrometer-thick films via physical vapor deposition. These systems are thermally stable and electro-optical-active films (r33 up to ∼20 pm/V) are prepared in few hours as a consequence of the pyridine-hydroxycarbonyl head-to-tail hydrogen bonding.
| Original language | English |
|---|---|
| Pages (from-to) | 183-194 |
| Number of pages | 12 |
| Journal | Nonlinear Optics Quantum Optics |
| Volume | 35 |
| Issue number | 1-3 |
| Publication status | Published - 2006 |
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Keywords
- Electrooptic
- Hydrogen bonding
- NLO
- Nonlinear optic
- Organic chromophore
- Push-pull
- PVD
ASJC Scopus subject areas
- Control and Systems Engineering
- Condensed Matter Physics
Cite this
Design and realization of new generations of organic chromophores for electro-optics. / Kang, Hu; Facchetti, Antonio; Jiang, Hua; Cariati, Elena; Righetto, Stefania; Ugo, Renato; Beverina, Luca; Morone, Marika; Pagani, Giorgio; Marks, Tobin J.
In: Nonlinear Optics Quantum Optics, Vol. 35, No. 1-3, 2006, p. 183-194.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Design and realization of new generations of organic chromophores for electro-optics
AU - Kang, Hu
AU - Facchetti, Antonio
AU - Jiang, Hua
AU - Cariati, Elena
AU - Righetto, Stefania
AU - Ugo, Renato
AU - Beverina, Luca
AU - Morone, Marika
AU - Pagani, Giorgio
AU - Marks, Tobin J
PY - 2006
Y1 - 2006
N2 - There is great current interest in developing molecule-based electro-optic (EO) materials for opto-electronic and photonic technologies such as high-speed optical communications, integrated optics, and optical data processing and storage. Here we present the design rationale, synthesis, and molecular properties of two new organic chromophore classes enabling very large EO response along with new methodologies for self-assembling them in a non-centrosymmetric fashion. In the first class, we demonstrate that disruption of the π-conjugation via a sterically-induced molecular twisting results in unusual molecular characteristics and unprecedented hyperpolarizabilities (μβ values as high as -488,000 × 10-48 esu at 1907 nm). Guest-host poled polymers containing π-twisted chromophores exhibit very large electro-optic coefficients (r33) up to 320 pm/V at 1310 nm. Molecules of the second class enable the fabrication of acentric, high-quality, transparent, micrometer-thick films via physical vapor deposition. These systems are thermally stable and electro-optical-active films (r33 up to ∼20 pm/V) are prepared in few hours as a consequence of the pyridine-hydroxycarbonyl head-to-tail hydrogen bonding.
AB - There is great current interest in developing molecule-based electro-optic (EO) materials for opto-electronic and photonic technologies such as high-speed optical communications, integrated optics, and optical data processing and storage. Here we present the design rationale, synthesis, and molecular properties of two new organic chromophore classes enabling very large EO response along with new methodologies for self-assembling them in a non-centrosymmetric fashion. In the first class, we demonstrate that disruption of the π-conjugation via a sterically-induced molecular twisting results in unusual molecular characteristics and unprecedented hyperpolarizabilities (μβ values as high as -488,000 × 10-48 esu at 1907 nm). Guest-host poled polymers containing π-twisted chromophores exhibit very large electro-optic coefficients (r33) up to 320 pm/V at 1310 nm. Molecules of the second class enable the fabrication of acentric, high-quality, transparent, micrometer-thick films via physical vapor deposition. These systems are thermally stable and electro-optical-active films (r33 up to ∼20 pm/V) are prepared in few hours as a consequence of the pyridine-hydroxycarbonyl head-to-tail hydrogen bonding.
KW - Electrooptic
KW - Hydrogen bonding
KW - NLO
KW - Nonlinear optic
KW - Organic chromophore
KW - Push-pull
KW - PVD
UR - http://www.scopus.com/inward/record.url?scp=33846325505&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33846325505&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33846325505
VL - 35
SP - 183
EP - 194
JO - Nonlinear Optics Quantum Optics
JF - Nonlinear Optics Quantum Optics
SN - 1543-0537
IS - 1-3
ER -