Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine)

Ren Zhang, Qihan Gong, Thomas J. Emge, Debasis Banerjee, Jing Li

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.

Original languageEnglish
Pages (from-to)393-396
Number of pages4
JournalChimia
Volume67
Issue number6
DOIs
Publication statusPublished - May 2013

Fingerprint

Bromine
Hydrogen
Polymers
Ethane
Metal ions
Ligands
Acids
isophthalate
pyridine

Keywords

  • 1D and 2D polymers
  • Coordination polymers
  • Isophthalic acid
  • N Ligands
  • Solvothermal reaction

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine). / Zhang, Ren; Gong, Qihan; Emge, Thomas J.; Banerjee, Debasis; Li, Jing.

In: Chimia, Vol. 67, No. 6, 05.2013, p. 393-396.

Research output: Contribution to journalArticle

Zhang, Ren ; Gong, Qihan ; Emge, Thomas J. ; Banerjee, Debasis ; Li, Jing. / Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine). In: Chimia. 2013 ; Vol. 67, No. 6. pp. 393-396.
@article{6e6958d60d6946b097a79f882ca365a9,
title = "Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine)",
abstract = "Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.",
keywords = "1D and 2D polymers, Coordination polymers, Isophthalic acid, N Ligands, Solvothermal reaction",
author = "Ren Zhang and Qihan Gong and Emge, {Thomas J.} and Debasis Banerjee and Jing Li",
year = "2013",
month = "5",
doi = "10.2533/chimia.2013.393",
language = "English",
volume = "67",
pages = "393--396",
journal = "Chimia",
issn = "0009-4293",
publisher = "Swiss Chemical Society",
number = "6",

}

TY - JOUR

T1 - Design and synthesis of new 1D and 2D R-isophthalic acid-based coordination polymers (R = hydrogen or bromine)

AU - Zhang, Ren

AU - Gong, Qihan

AU - Emge, Thomas J.

AU - Banerjee, Debasis

AU - Li, Jing

PY - 2013/5

Y1 - 2013/5

N2 - Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.

AB - Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.

KW - 1D and 2D polymers

KW - Coordination polymers

KW - Isophthalic acid

KW - N Ligands

KW - Solvothermal reaction

UR - http://www.scopus.com/inward/record.url?scp=84879612092&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84879612092&partnerID=8YFLogxK

U2 - 10.2533/chimia.2013.393

DO - 10.2533/chimia.2013.393

M3 - Article

VL - 67

SP - 393

EP - 396

JO - Chimia

JF - Chimia

SN - 0009-4293

IS - 6

ER -