Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry