Design in solid state synthesis based on phase homologies: A1-xSn9-xBi11+xSe26 (A=K, Rb, Cs) - A new member of the grand homologous series Am[M6Se8]m[M5+nSe 9+n] with M=Sn and Bi

Antje Mrotzek; Mercouri G Kanatzidis

doi:10.1016/S0022-4596(01)99482-4

Design in solid state synthesis based on phase homologies

A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi

Antje Mrotzek, Mercouri G Kanatzidis

Northwestern University

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

Both the composition and structure of A_1-xSn_9-xBi_11+xSe₂₆ (A = K, Rb, Cs) were predicted on the basis of the homologous series A_m[M₆Se₈]_mlM_5+nSe _9+n] (M=Sn, Bi) and targeted for synthesis. A_1-xSn_9-xBi_11+xSe₂₆ adopts a new structure type that fits the structural evolution of the homologous series.

Original language	English
Pages (from-to)	299-301
Number of pages	3
Journal	Journal of Solid State Chemistry
Volume	167
Issue number	2
DOIs	https://doi.org/10.1016/S0022-4596(01)99482-4
Publication status	Published - Sep 2002

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homology

solid state

synthesis

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ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

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Mrotzek, A., & Kanatzidis, M. G. (2002). Design in solid state synthesis based on phase homologies: A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi. Journal of Solid State Chemistry, 167(2), 299-301. https://doi.org/10.1016/S0022-4596(01)99482-4

Design in solid state synthesis based on phase homologies : A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi. / Mrotzek, Antje; Kanatzidis, Mercouri G.

In: Journal of Solid State Chemistry, Vol. 167, No. 2, 09.2002, p. 299-301.

Research output: Contribution to journal › Article

Mrotzek, A & Kanatzidis, MG 2002, 'Design in solid state synthesis based on phase homologies: A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi', Journal of Solid State Chemistry, vol. 167, no. 2, pp. 299-301. https://doi.org/10.1016/S0022-4596(01)99482-4

Mrotzek A, Kanatzidis MG. Design in solid state synthesis based on phase homologies: A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi. Journal of Solid State Chemistry. 2002 Sep;167(2):299-301. https://doi.org/10.1016/S0022-4596(01)99482-4

Mrotzek, Antje ; Kanatzidis, Mercouri G. / Design in solid state synthesis based on phase homologies : A_1-xSn_9-xBi_11+xSe₂₆ (A=K, Rb, Cs) - A new member of the grand homologous series A_m[M₆Se₈]_m[M_5+nSe _9+n] with M=Sn and Bi. In: Journal of Solid State Chemistry. 2002 ; Vol. 167, No. 2. pp. 299-301.

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10.1016/S0022-4596(01)99482-4