Abstract
Both the composition and structure of A1-xSn9-xBi11+xSe26 (A = K, Rb, Cs) were predicted on the basis of the homologous series Am[M6Se8]mlM5+nSe 9+n] (M=Sn, Bi) and targeted for synthesis. A1-xSn9-xBi11+xSe26 adopts a new structure type that fits the structural evolution of the homologous series.
| Original language | English |
|---|---|
| Pages (from-to) | 299-301 |
| Number of pages | 3 |
| Journal | Journal of Solid State Chemistry |
| Volume | 167 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Sep 2002 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Cite this
Mrotzek, A., & Kanatzidis, M. G. (2002). Design in solid state synthesis based on phase homologies: A1-xSn9-xBi11+xSe26 (A=K, Rb, Cs) - A new member of the grand homologous series Am[M6Se8]m[M5+nSe 9+n] with M=Sn and Bi. Journal of Solid State Chemistry, 167(2), 299-301. https://doi.org/10.1016/S0022-4596(01)99482-4