Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells

Hsinhan Tsai, Reza Asadpour, Jean Christophe Blancon, Constantinos C. Stoumpos, Jacky Even, Pulickel M. Ajayan, Mercouri G Kanatzidis, Muhammad Ashraful Alam, Aditya D. Mohite, Wanyi Nie

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

State-of-the-art quantum-well-based devices such as photovoltaics, photodetectors, and light-emission devices are enabled by understanding the nature and the exact mechanism of electronic charge transport. Ruddlesden-Popper phase halide perovskites are two-dimensional solution-processed quantum wells and have recently emerged as highly efficient semiconductors for solar cell approaching 14% in power conversion efficiency. However, further improvements will require an understanding of the charge transport mechanisms, which are currently unknown and further complicated by the presence of strongly bound excitons. Here, we unambiguously determine that dominant photocurrent collection is through electric field-assisted electron-hole pair separation and transport across the potential barriers. This is revealed by in-depth device characterization, coupled with comprehensive device modeling, which can self-consistently reproduce our experimental findings. These findings establish the fundamental guidelines for the molecular and device design for layered 2D perovskite-based photovoltaics and optoelectronic devices, and are relevant for other similar quantum-confined systems.

Original languageEnglish
Article number2130
JournalNature Communications
Volume9
Issue number1
DOIs
Publication statusPublished - Dec 1 2018

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Semiconductor quantum wells
Charge transfer
quantum wells
Equipment and Supplies
Light emission
Photodetectors
Photocurrents
electronics
Optoelectronic devices
Conversion efficiency
Solar cells
Electric fields
Semiconductor materials
Electrons
Equipment Design
Semiconductors
perovskites
optoelectronic devices
halides
light emission

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

Cite this

Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells. / Tsai, Hsinhan; Asadpour, Reza; Blancon, Jean Christophe; Stoumpos, Constantinos C.; Even, Jacky; Ajayan, Pulickel M.; Kanatzidis, Mercouri G; Alam, Muhammad Ashraful; Mohite, Aditya D.; Nie, Wanyi.

In: Nature Communications, Vol. 9, No. 1, 2130, 01.12.2018.

Research output: Contribution to journalArticle

Tsai, H, Asadpour, R, Blancon, JC, Stoumpos, CC, Even, J, Ajayan, PM, Kanatzidis, MG, Alam, MA, Mohite, AD & Nie, W 2018, 'Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells', Nature Communications, vol. 9, no. 1, 2130. https://doi.org/10.1038/s41467-018-04430-2
Tsai, Hsinhan ; Asadpour, Reza ; Blancon, Jean Christophe ; Stoumpos, Constantinos C. ; Even, Jacky ; Ajayan, Pulickel M. ; Kanatzidis, Mercouri G ; Alam, Muhammad Ashraful ; Mohite, Aditya D. ; Nie, Wanyi. / Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells. In: Nature Communications. 2018 ; Vol. 9, No. 1.
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