Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties

Huong Giang T Nguyen, Mitchell H. Weston, Amy A. Sarjeant, Daniel M. Gardner, Zhi An, Raanan Carmieli, Michael R Wasielewski, Omar K. Farha, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccessible, single-site vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of tert-butylhydroperoxide.

Original languageEnglish
Pages (from-to)3528-3534
Number of pages7
JournalCrystal Growth and Design
Volume13
Issue number8
DOIs
Publication statusPublished - Aug 7 2013

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tert-Butylhydroperoxide
struts
Vanadates
Struts
catalytic activity
Catalyst activity
Metals
porosity
Oxidation
oxidation
synthesis
metals
tetralin

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties. / Nguyen, Huong Giang T; Weston, Mitchell H.; Sarjeant, Amy A.; Gardner, Daniel M.; An, Zhi; Carmieli, Raanan; Wasielewski, Michael R; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: Crystal Growth and Design, Vol. 13, No. 8, 07.08.2013, p. 3528-3534.

Research output: Contribution to journalArticle

Nguyen, Huong Giang T ; Weston, Mitchell H. ; Sarjeant, Amy A. ; Gardner, Daniel M. ; An, Zhi ; Carmieli, Raanan ; Wasielewski, Michael R ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / Design, synthesis, characterization, and catalytic properties of a large-pore metal-organic framework possessing single-site vanadyl(monocatecholate) moieties. In: Crystal Growth and Design. 2013 ; Vol. 13, No. 8. pp. 3528-3534.
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