Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

Omar K. Farha; Christopher E. Wilmer; Ibrahim Eryazici; Brad G. Hauser; Philip A. Parilla; Kevin ONeill; Amy A. Sarjeant; Sonbinh T. Nguyen; Randall Q. Snurr; Joseph T Hupp

doi:10.1021/ja302623w

Designing higher surface area metal-organic frameworks

Are triple bonds better than phenyls?

Omar K. Farha, Christopher E. Wilmer, Ibrahim Eryazici, Brad G. Hauser, Philip A. Parilla, Kevin ONeill, Amy A. Sarjeant, Sonbinh T. Nguyen, Randall Q. Snurr, Joseph T Hupp

Northwestern University

Research output: Contribution to journal › Article

134 Citations (Scopus)

Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

Original language	English
Pages (from-to)	9860-9863
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	24
DOIs	https://doi.org/10.1021/ja302623w
Publication status	Published - Jun 20 2012

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Porosity

Hydrogen

Metals

Molecules

ASJC Scopus subject areas

Chemistry(all)
Catalysis
Biochemistry
Colloid and Surface Chemistry

Cite this

Farha, O. K., Wilmer, C. E., Eryazici, I., Hauser, B. G., Parilla, P. A., ONeill, K., ... Hupp, J. T. (2012). Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls? Journal of the American Chemical Society, 134(24), 9860-9863. https://doi.org/10.1021/ja302623w

Designing higher surface area metal-organic frameworks : Are triple bonds better than phenyls? / Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim; Hauser, Brad G.; Parilla, Philip A.; ONeill, Kevin; Sarjeant, Amy A.; Nguyen, Sonbinh T.; Snurr, Randall Q.; Hupp, Joseph T.

In: Journal of the American Chemical Society, Vol. 134, No. 24, 20.06.2012, p. 9860-9863.

Research output: Contribution to journal › Article

Farha, OK, Wilmer, CE, Eryazici, I, Hauser, BG, Parilla, PA, ONeill, K, Sarjeant, AA, Nguyen, ST, Snurr, RQ & Hupp, JT 2012, 'Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?', Journal of the American Chemical Society, vol. 134, no. 24, pp. 9860-9863. https://doi.org/10.1021/ja302623w

Farha OK, Wilmer CE, Eryazici I, Hauser BG, Parilla PA, ONeill K et al. Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls? Journal of the American Chemical Society. 2012 Jun 20;134(24):9860-9863. https://doi.org/10.1021/ja302623w

Farha, Omar K. ; Wilmer, Christopher E. ; Eryazici, Ibrahim ; Hauser, Brad G. ; Parilla, Philip A. ; ONeill, Kevin ; Sarjeant, Amy A. ; Nguyen, Sonbinh T. ; Snurr, Randall Q. ; Hupp, Joseph T. / Designing higher surface area metal-organic frameworks : Are triple bonds better than phenyls?. In: Journal of the American Chemical Society. 2012 ; Vol. 134, No. 24. pp. 9860-9863.

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10.1021/ja302623w