Abstract
We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.
| Original language | English |
|---|---|
| Pages (from-to) | 9860-9863 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 134 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - Jun 20 2012 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Designing higher surface area metal-organic frameworks : Are triple bonds better than phenyls? / Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim; Hauser, Brad G.; Parilla, Philip A.; ONeill, Kevin; Sarjeant, Amy A.; Nguyen, Sonbinh T.; Snurr, Randall Q.; Hupp, Joseph T.
In: Journal of the American Chemical Society, Vol. 134, No. 24, 20.06.2012, p. 9860-9863.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Designing higher surface area metal-organic frameworks
T2 - Are triple bonds better than phenyls?
AU - Farha, Omar K.
AU - Wilmer, Christopher E.
AU - Eryazici, Ibrahim
AU - Hauser, Brad G.
AU - Parilla, Philip A.
AU - ONeill, Kevin
AU - Sarjeant, Amy A.
AU - Nguyen, Sonbinh T.
AU - Snurr, Randall Q.
AU - Hupp, Joseph T
PY - 2012/6/20
Y1 - 2012/6/20
N2 - We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.
AB - We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.
UR - http://www.scopus.com/inward/record.url?scp=84862534248&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84862534248&partnerID=8YFLogxK
U2 - 10.1021/ja302623w
DO - 10.1021/ja302623w
M3 - Article
C2 - 22670563
AN - SCOPUS:84862534248
VL - 134
SP - 9860
EP - 9863
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 24
ER -