Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

Omar K. Farha, Christopher E. Wilmer, Ibrahim Eryazici, Brad G. Hauser, Philip A. Parilla, Kevin ONeill, Amy A. Sarjeant, Sonbinh T. Nguyen, Randall Q. Snurr, Joseph T Hupp

Research output: Contribution to journalArticle

134 Citations (Scopus)

Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

Original languageEnglish
Pages (from-to)9860-9863
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number24
DOIs
Publication statusPublished - Jun 20 2012

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Porosity
Hydrogen
Metals
Molecules

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Designing higher surface area metal-organic frameworks : Are triple bonds better than phenyls? / Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim; Hauser, Brad G.; Parilla, Philip A.; ONeill, Kevin; Sarjeant, Amy A.; Nguyen, Sonbinh T.; Snurr, Randall Q.; Hupp, Joseph T.

In: Journal of the American Chemical Society, Vol. 134, No. 24, 20.06.2012, p. 9860-9863.

Research output: Contribution to journalArticle

Farha, OK, Wilmer, CE, Eryazici, I, Hauser, BG, Parilla, PA, ONeill, K, Sarjeant, AA, Nguyen, ST, Snurr, RQ & Hupp, JT 2012, 'Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?', Journal of the American Chemical Society, vol. 134, no. 24, pp. 9860-9863. https://doi.org/10.1021/ja302623w
Farha, Omar K. ; Wilmer, Christopher E. ; Eryazici, Ibrahim ; Hauser, Brad G. ; Parilla, Philip A. ; ONeill, Kevin ; Sarjeant, Amy A. ; Nguyen, Sonbinh T. ; Snurr, Randall Q. ; Hupp, Joseph T. / Designing higher surface area metal-organic frameworks : Are triple bonds better than phenyls?. In: Journal of the American Chemical Society. 2012 ; Vol. 134, No. 24. pp. 9860-9863.
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