Designing surface-confined coordination oligomers

Marc Altman, Meital Rachamim, Takahiko Ichiki, Mark A. Iron, Guennadi Evmenenko, Pulak Dutta, Milko E. Van Der Boom

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13 Citations (Scopus)

Abstract

(Figure Presented) Designer materials: HOMO-LUMO engineering of coordination-based oligomers covalently bound to silicon or glass has been achieved by the use of a partially fluorinated chromophore (see graphic). The experimental and computationally derived physical chemical properties of these assemblies are compared to their non-fluorinated analogues.

Original languageEnglish
Pages (from-to)6744-6747
Number of pages4
JournalChemistry - A European Journal
Volume16
Issue number23
DOIs
Publication statusPublished - Jun 18 2010

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Keywords

  • Coordination polymers
  • Density functional calculations
  • HOMO-LUMO engineering
  • Oligomers
  • Solid-state structures

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

Cite this

Altman, M., Rachamim, M., Ichiki, T., Iron, M. A., Evmenenko, G., Dutta, P., & Van Der Boom, M. E. (2010). Designing surface-confined coordination oligomers. Chemistry - A European Journal, 16(23), 6744-6747. https://doi.org/10.1002/chem.201000690