Desulfurization of hydrocarbons by electron transfer oxidative polymerization of heteroaromatic sulfides catalyzed by H5PV 2Mo10O40 polyoxometalate

Alexander M. Khenkin, Ronny Neumann

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Gone in 7200 Seconds: Heteroaromatic thiophene derivatives, refractory to hydrodesulfurization, are removed from hydrocarbons by oxidative polymerization over H5PV2Mo10O40/SiO2 as a recyclable, heterogeneous catalyst. The levels of sulfur-containing compounds reach sub-ppm to nondetectable levels, as analyzed by gas chromatography with a flame photometric detector.

Original languageEnglish
Pages (from-to)346-348
Number of pages3
JournalChemSusChem
Volume4
Issue number3
DOIs
Publication statusPublished - Mar 21 2011

Fingerprint

Thiophenes
Hydrodesulfurization
sulfur compound
Sulfides
Thiophene
Desulfurization
Hydrocarbons
Sulfur
polymerization
Gas chromatography
Refractory materials
gas chromatography
catalyst
Polymerization
sulfide
hydrocarbon
Derivatives
Detectors
electron
Catalysts

Keywords

  • Desulfurization
  • Heterogeneous catalysis
  • Oxidation-polyoxometalates
  • Sulfides

ASJC Scopus subject areas

  • Energy(all)
  • Environmental Chemistry
  • Materials Science(all)
  • Chemical Engineering(all)

Cite this

Desulfurization of hydrocarbons by electron transfer oxidative polymerization of heteroaromatic sulfides catalyzed by H5PV 2Mo10O40 polyoxometalate. / Khenkin, Alexander M.; Neumann, Ronny.

In: ChemSusChem, Vol. 4, No. 3, 21.03.2011, p. 346-348.

Research output: Contribution to journalArticle

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