Abstract
Slowing of the dynamic interchange of bridge and terminal hydrogens in a metal tetrahydroborate has been observed for the first time in the low temperature 1H n.m.r. spectra of (C5H5) 3UBH4; at coalescence, ΔG* is ca. 5·0 ± 0·6 kcal mol-1 (21 ± 2·5 kJ mol -1).
| Original language | English |
|---|---|
| Pages (from-to) | 1019-1020 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Volume | 0 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 1972 |
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ASJC Scopus subject areas
- Molecular Medicine
Cite this
Detection of stereochemical nonrigidity in a metal tetrahydroborate and estimation of the barrier : 1H nuclear magnetic resonance study. / Marks, Tobin J; Kolb, John R.
In: Journal of the Chemical Society, Chemical Communications, Vol. 0, No. 18, 1972, p. 1019-1020.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Detection of stereochemical nonrigidity in a metal tetrahydroborate and estimation of the barrier
T2 - 1H nuclear magnetic resonance study
AU - Marks, Tobin J
AU - Kolb, John R.
PY - 1972
Y1 - 1972
N2 - Slowing of the dynamic interchange of bridge and terminal hydrogens in a metal tetrahydroborate has been observed for the first time in the low temperature 1H n.m.r. spectra of (C5H5) 3UBH4; at coalescence, ΔG* is ca. 5·0 ± 0·6 kcal mol-1 (21 ± 2·5 kJ mol -1).
AB - Slowing of the dynamic interchange of bridge and terminal hydrogens in a metal tetrahydroborate has been observed for the first time in the low temperature 1H n.m.r. spectra of (C5H5) 3UBH4; at coalescence, ΔG* is ca. 5·0 ± 0·6 kcal mol-1 (21 ± 2·5 kJ mol -1).
UR - http://www.scopus.com/inward/record.url?scp=37049121678&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049121678&partnerID=8YFLogxK
U2 - 10.1039/C39720001019
DO - 10.1039/C39720001019
M3 - Article
VL - 0
SP - 1019
EP - 1020
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 18
ER -