TY - JOUR
T1 - Detection of stereochemical nonrigidity in a metal tetrahydroborate and estimation of the barrier
T2 - 1H nuclear magnetic resonance study
AU - Marks, Tobin J
AU - Kolb, John R.
PY - 1972
Y1 - 1972
N2 - Slowing of the dynamic interchange of bridge and terminal hydrogens in a metal tetrahydroborate has been observed for the first time in the low temperature 1H n.m.r. spectra of (C5H5) 3UBH4; at coalescence, ΔG* is ca. 5·0 ± 0·6 kcal mol-1 (21 ± 2·5 kJ mol -1).
AB - Slowing of the dynamic interchange of bridge and terminal hydrogens in a metal tetrahydroborate has been observed for the first time in the low temperature 1H n.m.r. spectra of (C5H5) 3UBH4; at coalescence, ΔG* is ca. 5·0 ± 0·6 kcal mol-1 (21 ± 2·5 kJ mol -1).
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U2 - 10.1039/C39720001019
DO - 10.1039/C39720001019
M3 - Article
AN - SCOPUS:37049121678
VL - 0
SP - 1019
EP - 1020
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 18
ER -