Determination of the solution acidity of tris(trimethylsilyl) silane

Gady Korogodsky; Michael Bendikov; Dmitry Bravo-Zhivotovskii; Yitzhak Apeloig

doi:10.1021/om010821s

Determination of the solution acidity of tris(trimethylsilyl) silane

Gady Korogodsky, Michael Bendikov, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me₃Si)₃SiH was determined in diethyl ether solution by reactions of (Me₃Si)₃SiLi·3THF with a series of C-H acids. It was found that (Me₃Si)₃SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

Original language	English
Pages (from-to)	3157-3161
Number of pages	5
Journal	Organometallics
Volume	21
Issue number	15
DOIs	https://doi.org/10.1021/om010821s
Publication status	Published - Jul 22 2002

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om010821s

Fingerprint Dive into the research topics of 'Determination of the solution acidity of tris(trimethylsilyl) silane'. Together they form a unique fingerprint.

Cite this

@article{b3fcc817712a4980b0cc6c6185c81ff4,

title = "Determination of the solution acidity of tris(trimethylsilyl) silane",

abstract = "The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.",

author = "Gady Korogodsky and Michael Bendikov and Dmitry Bravo-Zhivotovskii and Yitzhak Apeloig",

year = "2002",

month = jul,

day = "22",

doi = "10.1021/om010821s",

language = "English",

volume = "21",

pages = "3157--3161",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Determination of the solution acidity of tris(trimethylsilyl) silane

AU - Korogodsky, Gady

AU - Bendikov, Michael

AU - Bravo-Zhivotovskii, Dmitry

AU - Apeloig, Yitzhak

PY - 2002/7/22

Y1 - 2002/7/22

N2 - The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

AB - The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

UR - http://www.scopus.com/inward/record.url?scp=0037668662&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037668662&partnerID=8YFLogxK

U2 - 10.1021/om010821s

DO - 10.1021/om010821s

M3 - Article

AN - SCOPUS:0037668662

VL - 21

SP - 3157

EP - 3161

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 15

ER -

Determination of the solution acidity of tris(trimethylsilyl) silane

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this