Determination of the solution acidity of tris(trimethylsilyl) silane

Gady Korogodsky; Michael Bendikov; Dmitry Bravo-Zhivotovskii; Yitzhak Apeloig

doi:10.1021/om010821s

Determination of the solution acidity of tris(trimethylsilyl) silane

Gady Korogodsky, Michael Bendikov, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me₃Si)₃SiH was determined in diethyl ether solution by reactions of (Me₃Si)₃SiLi·3THF with a series of C-H acids. It was found that (Me₃Si)₃SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

Original language	English
Pages (from-to)	3157-3161
Number of pages	5
Journal	Organometallics
Volume	21
Issue number	15
DOIs	https://doi.org/10.1021/om010821s
Publication status	Published - Jul 22 2002

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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AB - The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

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