Determination of the solution acidity of tris(trimethylsilyl) silane

Gady Korogodsky, Michael Bendikov, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

Original languageEnglish
Pages (from-to)3157-3161
Number of pages5
JournalOrganometallics
Volume21
Issue number15
DOIs
Publication statusPublished - Jul 22 2002

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Silanes
Acidity
acidity
silanes
diethyl ether
Ether
acids

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Determination of the solution acidity of tris(trimethylsilyl) silane. / Korogodsky, Gady; Bendikov, Michael; Bravo-Zhivotovskii, Dmitry; Apeloig, Yitzhak.

In: Organometallics, Vol. 21, No. 15, 22.07.2002, p. 3157-3161.

Research output: Contribution to journalArticle

Korogodsky, G, Bendikov, M, Bravo-Zhivotovskii, D & Apeloig, Y 2002, 'Determination of the solution acidity of tris(trimethylsilyl) silane', Organometallics, vol. 21, no. 15, pp. 3157-3161. https://doi.org/10.1021/om010821s
Korogodsky, Gady ; Bendikov, Michael ; Bravo-Zhivotovskii, Dmitry ; Apeloig, Yitzhak. / Determination of the solution acidity of tris(trimethylsilyl) silane. In: Organometallics. 2002 ; Vol. 21, No. 15. pp. 3157-3161.
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