Determination of the solution acidity of tris(trimethylsilyl) silane

Gady Korogodsky, Michael Bendikov, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

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Abstract

The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

Original languageEnglish
Pages (from-to)3157-3161
Number of pages5
JournalOrganometallics
Volume21
Issue number15
DOIs
Publication statusPublished - Jul 22 2002

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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