Determination of the solution acidity of tris(trimethylsilyl) silane

Gady Korogodsky, Michael Bendikov, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

Original languageEnglish
Pages (from-to)3157-3161
Number of pages5
JournalOrganometallics
Volume21
Issue number15
DOIs
Publication statusPublished - Jul 22 2002

Fingerprint

Silanes
Acidity
acidity
silanes
diethyl ether
Ether
acids

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Korogodsky, G., Bendikov, M., Bravo-Zhivotovskii, D., & Apeloig, Y. (2002). Determination of the solution acidity of tris(trimethylsilyl) silane. Organometallics, 21(15), 3157-3161. https://doi.org/10.1021/om010821s

Determination of the solution acidity of tris(trimethylsilyl) silane. / Korogodsky, Gady; Bendikov, Michael; Bravo-Zhivotovskii, Dmitry; Apeloig, Yitzhak.

In: Organometallics, Vol. 21, No. 15, 22.07.2002, p. 3157-3161.

Research output: Contribution to journal › Article

Korogodsky, G, Bendikov, M, Bravo-Zhivotovskii, D & Apeloig, Y 2002, 'Determination of the solution acidity of tris(trimethylsilyl) silane', Organometallics, vol. 21, no. 15, pp. 3157-3161. https://doi.org/10.1021/om010821s
Korogodsky G, Bendikov M, Bravo-Zhivotovskii D, Apeloig Y. Determination of the solution acidity of tris(trimethylsilyl) silane. Organometallics. 2002 Jul 22;21(15):3157-3161. https://doi.org/10.1021/om010821s
Korogodsky, Gady ; Bendikov, Michael ; Bravo-Zhivotovskii, Dmitry ; Apeloig, Yitzhak. / Determination of the solution acidity of tris(trimethylsilyl) silane. In: Organometallics. 2002 ; Vol. 21, No. 15. pp. 3157-3161.
@article{b3fcc817712a4980b0cc6c6185c81ff4,
title = "Determination of the solution acidity of tris(trimethylsilyl) silane",
abstract = "The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.",
author = "Gady Korogodsky and Michael Bendikov and Dmitry Bravo-Zhivotovskii and Yitzhak Apeloig",
year = "2002",
month = "7",
day = "22",
doi = "10.1021/om010821s",
language = "English",
volume = "21",
pages = "3157--3161",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "15",

}

TY - JOUR

T1 - Determination of the solution acidity of tris(trimethylsilyl) silane

AU - Korogodsky, Gady

AU - Bendikov, Michael

AU - Bravo-Zhivotovskii, Dmitry

AU - Apeloig, Yitzhak

PY - 2002/7/22

Y1 - 2002/7/22

N2 - The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

AB - The determination of the solution acidity of tris(trimethylsilyl)silane was performed. The acidity of (Me3Si)3SiH was determined in diethyl ether solution by reactions of (Me3Si)3SiLi·3THF with a series of C-H acids. It was found that (Me3Si)3SiH and 9-phenylxanthyllithium formed an equilibrium mixture in diethyl ether solution.

UR - http://www.scopus.com/inward/record.url?scp=0037668662&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037668662&partnerID=8YFLogxK

U2 - 10.1021/om010821s

DO - 10.1021/om010821s

M3 - Article

AN - SCOPUS:0037668662

VL - 21

SP - 3157

EP - 3161

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 15

ER -

Access to Document