Development of electrocatalysts for carbon dioxide reduction using polydentate ligands to probe structure-activity relationships

Daniel L. DuBois

doi:10.1016/s0167-2991(98)80725-8

Development of electrocatalysts for carbon dioxide reduction using polydentate ligands to probe structure-activity relationships

Daniel L. DuBois

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

This paper describes the use of polydentate ligands to optimize the performance of palladium catalysts for CO₂ reduction and to probe mechanistic aspects of catalytic reactions. Polydentate ligands can be used to precisely control coordination environments, electronic properties, and specific steric interactions that can lead to new insights into the relationship between catalyst structure and activity.

Original language	English
Pages (from-to)	43-53
Number of pages	11
Journal	Studies in Surface Science and Catalysis
Volume	114
DOIs	https://doi.org/10.1016/s0167-2991(98)80725-8
Publication status	Published - 1998

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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abstract = "This paper describes the use of polydentate ligands to optimize the performance of palladium catalysts for CO2 reduction and to probe mechanistic aspects of catalytic reactions. Polydentate ligands can be used to precisely control coordination environments, electronic properties, and specific steric interactions that can lead to new insights into the relationship between catalyst structure and activity.",

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