Diels-Alder reaction of acenes with singlet and triplet oxygen - Theoretical study of two-state reactivity

A. Ravikumar Reddy, Michael Bendikov

Research output: Contribution to journalArticle

96 Citations (Scopus)

Abstract

An interesting change in mechanism (from concerted to biradical) is described for the reaction of acenes (benzene through pentacene) with molecular oxygen (either singlet oxygen, 1Δg-O2, or triplet oxygen, 3Σ-g-O2).

Original languageEnglish
Pages (from-to)1179-1181
Number of pages3
JournalChemical Communications
Issue number11
DOIs
Publication statusPublished - 2006

Fingerprint

Singlet Oxygen
Molecular oxygen
Benzene
Oxygen
pentacene

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Diels-Alder reaction of acenes with singlet and triplet oxygen - Theoretical study of two-state reactivity. / Reddy, A. Ravikumar; Bendikov, Michael.

In: Chemical Communications, No. 11, 2006, p. 1179-1181.

Research output: Contribution to journalArticle

@article{be0b26a6ea8a40b2bd48d360830fc6cd,
title = "Diels-Alder reaction of acenes with singlet and triplet oxygen - Theoretical study of two-state reactivity",
abstract = "An interesting change in mechanism (from concerted to biradical) is described for the reaction of acenes (benzene through pentacene) with molecular oxygen (either singlet oxygen, 1Δg-O2, or triplet oxygen, 3Σ-g-O2).",
author = "Reddy, {A. Ravikumar} and Michael Bendikov",
year = "2006",
doi = "10.1039/b513597d",
language = "English",
pages = "1179--1181",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "11",

}

TY - JOUR

T1 - Diels-Alder reaction of acenes with singlet and triplet oxygen - Theoretical study of two-state reactivity

AU - Reddy, A. Ravikumar

AU - Bendikov, Michael

PY - 2006

Y1 - 2006

N2 - An interesting change in mechanism (from concerted to biradical) is described for the reaction of acenes (benzene through pentacene) with molecular oxygen (either singlet oxygen, 1Δg-O2, or triplet oxygen, 3Σ-g-O2).

AB - An interesting change in mechanism (from concerted to biradical) is described for the reaction of acenes (benzene through pentacene) with molecular oxygen (either singlet oxygen, 1Δg-O2, or triplet oxygen, 3Σ-g-O2).

UR - http://www.scopus.com/inward/record.url?scp=33644777817&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33644777817&partnerID=8YFLogxK

U2 - 10.1039/b513597d

DO - 10.1039/b513597d

M3 - Article

AN - SCOPUS:33644777817

SP - 1179

EP - 1181

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 11

ER -