Diethyl sulfide stabilization of platinum-complex catalysts for hydrosilylation of olefins

Christopher M. Downing, Harold H Kung

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Addition of excess diethylsulfide to the Karstedt catalyst prevents agglomeration of Pt and results in higher reaction rates for hydrosilylation of olefins. The beneficial effects were very pronounced in the hydrosilylation of trimethylsilyl-4-pentenoate with tetrakis(dimethylsilylethyl)silane, where 57% yield was obtained compared with 10% without diethylsulfide. Enhanced activity was also observed in the hydrosilylation of tetravinylsilane, vinyltrimethylsilane, and 1-hexene with chlorodimethylsilane.

Original languageEnglish
Pages (from-to)1166-1169
Number of pages4
JournalCatalysis Communications
Volume12
Issue number12
DOIs
Publication statusPublished - Jul 1 2011

Fingerprint

Hydrosilylation
Alkenes
Platinum
Olefins
Stabilization
Catalysts
Silanes
Reaction rates
Agglomeration
diethyl sulfide
Sulfides

Keywords

  • Deactivation
  • Diethylsulfide
  • Hydrosilylation
  • Karstedt catalyst
  • Platinum
  • Stabilization

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Chemistry(all)

Cite this

Diethyl sulfide stabilization of platinum-complex catalysts for hydrosilylation of olefins. / Downing, Christopher M.; Kung, Harold H.

In: Catalysis Communications, Vol. 12, No. 12, 01.07.2011, p. 1166-1169.

Research output: Contribution to journalArticle

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