Dinitrogen complexes of pincer-ligated iridium

Rajshekhar Ghosh, Mira Kanzelberger, Thomas J. Emge, Gene S. Hall, Alan S Goldman

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Precursors of the fragment (PCP)Ir have been previously reported to react with dinitrogen to give the bridging dinuclear complex [(PCP)Ir] 2(N 2) (2), which was crystallographically characterized. We report that under N 2 atmosphere the only observable nitrogen complex in solution is actually the terminal dinitrogen complex (PCP)Ir(N 2). The mono- and dinuclear species are in equilibrium; the dinuclear complex more readily crystallizes from solution.

Original languageEnglish
Pages (from-to)5668-5671
Number of pages4
JournalOrganometallics
Volume25
Issue number23
DOIs
Publication statusPublished - Nov 6 2006

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Iridium
iridium
Nitrogen
fragments
nitrogen
atmospheres

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Ghosh, R., Kanzelberger, M., Emge, T. J., Hall, G. S., & Goldman, A. S. (2006). Dinitrogen complexes of pincer-ligated iridium. Organometallics, 25(23), 5668-5671. https://doi.org/10.1021/om0607043

Dinitrogen complexes of pincer-ligated iridium. / Ghosh, Rajshekhar; Kanzelberger, Mira; Emge, Thomas J.; Hall, Gene S.; Goldman, Alan S.

In: Organometallics, Vol. 25, No. 23, 06.11.2006, p. 5668-5671.

Research output: Contribution to journalArticle

Ghosh, R, Kanzelberger, M, Emge, TJ, Hall, GS & Goldman, AS 2006, 'Dinitrogen complexes of pincer-ligated iridium', Organometallics, vol. 25, no. 23, pp. 5668-5671. https://doi.org/10.1021/om0607043
Ghosh R, Kanzelberger M, Emge TJ, Hall GS, Goldman AS. Dinitrogen complexes of pincer-ligated iridium. Organometallics. 2006 Nov 6;25(23):5668-5671. https://doi.org/10.1021/om0607043
Ghosh, Rajshekhar ; Kanzelberger, Mira ; Emge, Thomas J. ; Hall, Gene S. ; Goldman, Alan S. / Dinitrogen complexes of pincer-ligated iridium. In: Organometallics. 2006 ; Vol. 25, No. 23. pp. 5668-5671.
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