Direct aerobic oxidation of secondary alcohols catalysed by Pt(0) nanoparticles stabilized by PV2Mo10O40 5- polyoxmetalate

Galia Maayan, Ronny Neumann

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Pt(0) nanoparticles stabilized by the H5PV2Mo 10O40 polyoxometalate were prepared in water by a sequence of redox reactions and supported on α-alumina. Characterization by TEM showed an average particle size of 2.6 nm with an approximate size dispersion of about ±25%. EDS analysis confirmed the amounts of metal and polyoxometalate as indicated from the reaction stoichiometry. These nanoparticles were further used as catalysts for the oxidation of secondary alcohols with molecular oxygen to the corresponding carbonyl products. The oxidation of secondary alcohols was further improved by the use of Pt nanoparticles stabilized by Rh1.7PV2Mo10O 40.

Original languageEnglish
Pages (from-to)41-45
Number of pages5
JournalCatalysis Letters
Volume123
Issue number1-2
DOIs
Publication statusPublished - Jun 2008

Fingerprint

alcohols
Alcohols
Nanoparticles
Oxidation
nanoparticles
oxidation
Molecular oxygen
Aluminum Oxide
Redox reactions
Stoichiometry
Energy dispersive spectroscopy
stoichiometry
Alumina
aluminum oxides
Metals
Particle size
Transmission electron microscopy
catalysts
transmission electron microscopy
Catalysts

Keywords

  • Alcohols
  • Colloids
  • Nanoparticles
  • Oxidation
  • Oxygen
  • Pt

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Direct aerobic oxidation of secondary alcohols catalysed by Pt(0) nanoparticles stabilized by PV2Mo10O40 5- polyoxmetalate. / Maayan, Galia; Neumann, Ronny.

In: Catalysis Letters, Vol. 123, No. 1-2, 06.2008, p. 41-45.

Research output: Contribution to journalArticle

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