Abstract
The synthesis of terminal as well as internal olefins was achieved by the one-step olefination of alcohols with sulfones catalyzed by a ruthenium pincer complex. Furthermore performing the reaction with dimethyl sulfone under mild hydrogen pressure provides a direct route for the replacement of alcohol hydroxy groups by methyl groups in one step.
| Original language | English |
|---|---|
| Pages (from-to) | 11092-11095 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 53 |
| Issue number | 41 |
| DOIs | |
| Publication status | Published - Oct 6 2014 |
Fingerprint
Keywords
- homogeneous catalysis
- olefination
- pincer complexes
- ruthenium
- stilbenes
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
Cite this
Direct catalytic olefination of alcohols with sulfones. / Srimani, Dipankar; Leitus, Gregory; Ben-David, Yehoshoa; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 53, No. 41, 06.10.2014, p. 11092-11095.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Direct catalytic olefination of alcohols with sulfones
AU - Srimani, Dipankar
AU - Leitus, Gregory
AU - Ben-David, Yehoshoa
AU - Milstein, David
PY - 2014/10/6
Y1 - 2014/10/6
N2 - The synthesis of terminal as well as internal olefins was achieved by the one-step olefination of alcohols with sulfones catalyzed by a ruthenium pincer complex. Furthermore performing the reaction with dimethyl sulfone under mild hydrogen pressure provides a direct route for the replacement of alcohol hydroxy groups by methyl groups in one step.
AB - The synthesis of terminal as well as internal olefins was achieved by the one-step olefination of alcohols with sulfones catalyzed by a ruthenium pincer complex. Furthermore performing the reaction with dimethyl sulfone under mild hydrogen pressure provides a direct route for the replacement of alcohol hydroxy groups by methyl groups in one step.
KW - homogeneous catalysis
KW - olefination
KW - pincer complexes
KW - ruthenium
KW - stilbenes
UR - http://www.scopus.com/inward/record.url?scp=85027934360&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85027934360&partnerID=8YFLogxK
U2 - 10.1002/anie.201407281
DO - 10.1002/anie.201407281
M3 - Article
VL - 53
SP - 11092
EP - 11095
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 41
ER -