Direct imaging of surface-enhanced Raman scattering in the near field

Peng Zhang, Steve Smith, Garry Rumbles, Michael E. Himmel

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

By using near-field scanning microscopy/spectroscopy, we show that surface-enhanced Raman scattering (SERS) of rhodamine 6G deposited on self-affine silver colloidal film is localized to small, down to less than 200 nm, portions of the film. The locus of the SERS signals ("hot spots") does not necessarily reside in special topographic elements such as interstices and between nanoparticles. The local SERS enhancement is estimated to be over 3 orders of magnitude higher compared to the far-field measurements. Near-field imaging of SERS directly validates the theory of the optical response of self-affine fractal objects.

Original languageEnglish
Pages (from-to)520-523
Number of pages4
JournalLangmuir
Volume21
Issue number2
DOIs
Publication statusPublished - Jan 18 2005

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ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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