Direct observation of vast off-stoichiometric defects in single crystalline SnSe

Di Wu, Lijun Wu, Dongsheng He, Li Dong Zhao, Wei Li, Minghui Wu, Min Jin, Jingtao Xu, Jun Jiang, Li Huang, Yimei Zhu, Mercouri G Kanatzidis, Jiaqing He

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Single crystalline tin selenide (SnSe) recently emerged as a very promising thermoelectric material for waste heat harvesting and thermoelectric cooling, due to its record high figure of merit ZT in mediate temperature range. The most striking feature of SnSe lies in its extremely low lattice thermal conductivity as ascribed to the anisotropic and highly distorted Sn-Se bonds as well as the giant bond anharmonicity by previous studies, yet no theoretical models so far can give a quantitative explanation to such low a lattice thermal conductivity. In this work, we presented direct observation of an astonishingly vast number of off-stoichiometric Sn vacancies and Se interstitials, using sophisticated aberration corrected scanning transmission electron microscope; and credited the previously reported ultralow thermal conductivity of the SnSe single crystalline samples partly to their off-stoichiometric feature. To further validate the conclusion, we also synthesized stoichiometric SnSe single crystalline samples, and illustrated that the lattice thermal conductivity is deed much higher as compared with the off-stoichiometric single crystals. The scattering efficiency of individual point defect on heat-carrying phonons was then discussed in the state-of-art Debye-Callaway model.

Original languageEnglish
Pages (from-to)321-330
Number of pages10
JournalNano Energy
Volume35
DOIs
Publication statusPublished - May 1 2017

Fingerprint

Thermal conductivity
Crystalline materials
Defects
Tin
Waste heat
Point defects
Phonons
Aberrations
Crystal lattices
Vacancies
Electron microscopes
Single crystals
Scattering
Cooling
Scanning
Temperature

Keywords

  • Interstitial defects
  • Lattice thermal conductivity
  • Off-stoichiometry
  • SnSe
  • Thermoelectricity
  • Transmission electron microscopy

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)
  • Electrical and Electronic Engineering

Cite this

Direct observation of vast off-stoichiometric defects in single crystalline SnSe. / Wu, Di; Wu, Lijun; He, Dongsheng; Zhao, Li Dong; Li, Wei; Wu, Minghui; Jin, Min; Xu, Jingtao; Jiang, Jun; Huang, Li; Zhu, Yimei; Kanatzidis, Mercouri G; He, Jiaqing.

In: Nano Energy, Vol. 35, 01.05.2017, p. 321-330.

Research output: Contribution to journalArticle

Wu, D, Wu, L, He, D, Zhao, LD, Li, W, Wu, M, Jin, M, Xu, J, Jiang, J, Huang, L, Zhu, Y, Kanatzidis, MG & He, J 2017, 'Direct observation of vast off-stoichiometric defects in single crystalline SnSe', Nano Energy, vol. 35, pp. 321-330. https://doi.org/10.1016/j.nanoen.2017.04.004
Wu, Di ; Wu, Lijun ; He, Dongsheng ; Zhao, Li Dong ; Li, Wei ; Wu, Minghui ; Jin, Min ; Xu, Jingtao ; Jiang, Jun ; Huang, Li ; Zhu, Yimei ; Kanatzidis, Mercouri G ; He, Jiaqing. / Direct observation of vast off-stoichiometric defects in single crystalline SnSe. In: Nano Energy. 2017 ; Vol. 35. pp. 321-330.
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