Abstract
Herein, the first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to selectively form functionalized 1,2,5-substituted pyrroles liberating water and hydrogen gas as the sole by-products is presented. The reaction is catalyzed by pincer complexes of earth-abundant cobalt.
| Original language | English |
|---|---|
| Pages (from-to) | 14373-14377 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 55 |
| Issue number | 46 |
| DOIs | |
| Publication status | Published - 2016 |
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Keywords
- cobalt
- dehydrogenative coupling
- pincer complexes
- pyrroles
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
Cite this
Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes. / Daw, Prosenjit; Chakraborty, Subrata; Garg, Jai Anand; Ben-David, Yehoshoa; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 55, No. 46, 2016, p. 14373-14377.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes
AU - Daw, Prosenjit
AU - Chakraborty, Subrata
AU - Garg, Jai Anand
AU - Ben-David, Yehoshoa
AU - Milstein, David
PY - 2016
Y1 - 2016
N2 - Herein, the first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to selectively form functionalized 1,2,5-substituted pyrroles liberating water and hydrogen gas as the sole by-products is presented. The reaction is catalyzed by pincer complexes of earth-abundant cobalt.
AB - Herein, the first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to selectively form functionalized 1,2,5-substituted pyrroles liberating water and hydrogen gas as the sole by-products is presented. The reaction is catalyzed by pincer complexes of earth-abundant cobalt.
KW - cobalt
KW - dehydrogenative coupling
KW - pincer complexes
KW - pyrroles
UR - http://www.scopus.com/inward/record.url?scp=84993993794&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84993993794&partnerID=8YFLogxK
U2 - 10.1002/anie.201607742
DO - 10.1002/anie.201607742
M3 - Article
VL - 55
SP - 14373
EP - 14377
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 46
ER -