Direction to practical production of hydrogen by formic acid dehydrogenation with Cp∗Ir complexes bearing imidazoline ligands

Naoya Onishi, Mehmed Z. Ertem, Shaoan Xu, Akihiro Tsurusaki, Yuichi Manaka, James Muckerman, Etsuko Fujita, Yuichiro Himeda

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

A Cp∗Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m3 of H2/CO2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. The pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.

Original languageEnglish
Pages (from-to)988-992
Number of pages5
JournalCatalysis Science and Technology
Volume6
Issue number4
DOIs
Publication statusPublished - 2016

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formic acid
Bearings (structural)
Imidazolines
Formic acid
Dehydrogenation
Hydrogen
Ligands
Gases
Direction compound

ASJC Scopus subject areas

  • Catalysis

Cite this

Direction to practical production of hydrogen by formic acid dehydrogenation with Cp∗Ir complexes bearing imidazoline ligands. / Onishi, Naoya; Ertem, Mehmed Z.; Xu, Shaoan; Tsurusaki, Akihiro; Manaka, Yuichi; Muckerman, James; Fujita, Etsuko; Himeda, Yuichiro.

In: Catalysis Science and Technology, Vol. 6, No. 4, 2016, p. 988-992.

Research output: Contribution to journalArticle

Onishi, Naoya ; Ertem, Mehmed Z. ; Xu, Shaoan ; Tsurusaki, Akihiro ; Manaka, Yuichi ; Muckerman, James ; Fujita, Etsuko ; Himeda, Yuichiro. / Direction to practical production of hydrogen by formic acid dehydrogenation with Cp∗Ir complexes bearing imidazoline ligands. In: Catalysis Science and Technology. 2016 ; Vol. 6, No. 4. pp. 988-992.
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