Direction to practical production of hydrogen by formic acid dehydrogenation with Cp∗Ir complexes bearing imidazoline ligands

Naoya Onishi, Mehmed Z. Ertem, Shaoan Xu, Akihiro Tsurusaki, Yuichi Manaka, James Muckerman, Etsuko Fujita, Yuichiro Himeda

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Abstract

A Cp∗Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m3 of H2/CO2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. The pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.

Original languageEnglish
Pages (from-to)988-992
Number of pages5
JournalCatalysis Science and Technology
Volume6
Issue number4
DOIs
Publication statusPublished - 2016

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ASJC Scopus subject areas

  • Catalysis

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