Dispersible gold nanorod dimers with sub-5 nm gaps as local amplifiers for surface-enhanced Raman scattering

Kyle D. Osberg, Matthew Rycenga, Nadine Harris, Abrin L. Schmucker, Mark R. Langille, George C Schatz, Chad A. Mirkin

Research output: Contribution to journalArticle

102 Citations (Scopus)

Abstract

We report the synthesis of solution-dispersible, 35 nm diameter gold nanorod dimers with gaps as small as ∼2 nm for surface-enhanced Raman scattering (SERS). Using on-wire lithography (OWL), we prepared tailorable dimers in high yield and high monodispersity (∼96% dimers) that produce both large and reproducible SERS signals with enhancement factors of (6.8 ± 0.7) × 10 8 for single dimers in air and 1.2 × 10 6 for ensemble-averaged solution measurements. Furthermore, we show that these structures, which are the smallest ever made by OWL, can be used to detect molecules on flat surfaces and in aqueous solutions. When combined, these attributes with respect to sensitivity, reproducibility, and tailorability lead to a novel and powerful local amplification system for SERS applications.

Original languageEnglish
Pages (from-to)3828-3832
Number of pages5
JournalNano Letters
Volume12
Issue number7
DOIs
Publication statusPublished - Jul 11 2012

Fingerprint

Nanorods
Gold
Dimers
nanorods
Raman scattering
amplifiers
dimers
Raman spectra
gold
Lithography
lithography
wire
Wire
Amplification
flat surfaces
aqueous solutions
Molecules
augmentation
sensitivity
air

Keywords

  • gold nanorods
  • nanoparticle arrays
  • On-wire lithography
  • plasmonic dimers
  • surface-enhanced Raman scattering

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanical Engineering

Cite this

Osberg, K. D., Rycenga, M., Harris, N., Schmucker, A. L., Langille, M. R., Schatz, G. C., & Mirkin, C. A. (2012). Dispersible gold nanorod dimers with sub-5 nm gaps as local amplifiers for surface-enhanced Raman scattering. Nano Letters, 12(7), 3828-3832. https://doi.org/10.1021/nl301793k

Dispersible gold nanorod dimers with sub-5 nm gaps as local amplifiers for surface-enhanced Raman scattering. / Osberg, Kyle D.; Rycenga, Matthew; Harris, Nadine; Schmucker, Abrin L.; Langille, Mark R.; Schatz, George C; Mirkin, Chad A.

In: Nano Letters, Vol. 12, No. 7, 11.07.2012, p. 3828-3832.

Research output: Contribution to journalArticle

Osberg, KD, Rycenga, M, Harris, N, Schmucker, AL, Langille, MR, Schatz, GC & Mirkin, CA 2012, 'Dispersible gold nanorod dimers with sub-5 nm gaps as local amplifiers for surface-enhanced Raman scattering', Nano Letters, vol. 12, no. 7, pp. 3828-3832. https://doi.org/10.1021/nl301793k
Osberg, Kyle D. ; Rycenga, Matthew ; Harris, Nadine ; Schmucker, Abrin L. ; Langille, Mark R. ; Schatz, George C ; Mirkin, Chad A. / Dispersible gold nanorod dimers with sub-5 nm gaps as local amplifiers for surface-enhanced Raman scattering. In: Nano Letters. 2012 ; Vol. 12, No. 7. pp. 3828-3832.
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