Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water

Benjamin D. Matson, Colin T. Carver, Amber Von Ruden, Jenny Y. Yang, Simone Raugei, James M. Mayer

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

Fe(iii)-meso-tetra(pyridyl)porphyrins are electrocatalysts for the reduction of dioxygen in aqueous acidic solution. The 2-pyridyl derivatives, both the triflate and chloride salts, are more selective for the desired 4e- reduction than the isomeric 4-pyridyl complexes. The inward-pointing pyridinium groups influence proton delivery despite their distance from the iron centre.

Original languageEnglish
Pages (from-to)11100-11102
Number of pages3
JournalChemical Communications
Volume48
Issue number90
DOIs
Publication statusPublished - Oct 17 2012

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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