Diverse pathways in ring-opening Ziegler polymerization of an annulated methylenecyclopropane. A new single-site chain transfer mechanism

Tryg R. Jensen, Tobin J Marks

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

A single-site chain transfer mechanism was proposed for ring-opening Ziegler polymerization of an annulated methylenecyclopropane. All copolymerizations were run with a psuedo-first-order excess of monomer concentration. Polymerizations with all catalysts examined indicated decreased product molecular weight with increased concentration of 7-methylenebicyclo[4.1.0]heptane.

Original languageEnglish
Pages (from-to)1775-1778
Number of pages4
JournalMacromolecules
Volume36
Issue number6
DOIs
Publication statusPublished - Mar 25 2003

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Heptanes
Ring opening polymerization
Heptane
Copolymerization
Monomers
Molecular weight
Polymerization
Catalysts
methylenecyclopropane

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Diverse pathways in ring-opening Ziegler polymerization of an annulated methylenecyclopropane. A new single-site chain transfer mechanism. / Jensen, Tryg R.; Marks, Tobin J.

In: Macromolecules, Vol. 36, No. 6, 25.03.2003, p. 1775-1778.

Research output: Contribution to journalArticle

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