Dopant-Free Tetrakis-Triphenylamine Hole Transporting Material for Efficient Tin-Based Perovskite Solar Cells

Weijun Ke, Pragya Priyanka, Sureshraju Vegiraju, Constantinos C. Stoumpos, Ioannis Spanopoulos, Chan Myae Myae Soe, Tobin J Marks, Ming Chou Chen, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Developing dopant-free hole transporting layers (HTLs) is critical in achieving high-performance and robust state-of-the-art perovskite photovoltaics, especially for the air-sensitive tin-based perovskite systems. The commonly used HTLs require hygroscopic dopants and additives for optimal performance, which adds extra cost to manufacturing and limits long-term device stability. Here we demonstrate the use of a novel tetrakis-triphenylamine (TPE) small molecule prepared by a facile synthetic route as a superior dopant-free HTL for lead-free tin-based perovskite solar cells. The best-performing tin iodide perovskite cells employing the novel mixed-cation ethylenediammonium/formamidinium with the dopant-free TPE HTL achieve a power conversion efficiency as high as 7.23%, ascribed to the HTL's suitable band alignment and excellent hole extraction/collection properties. This efficiency is one of the highest reported so far for tin halide perovskite systems, highlighting potential application of TPE HTL material in low-cost high-performance tin-based perovskite solar cells.

Original languageEnglish
Pages (from-to)388-393
Number of pages6
JournalJournal of the American Chemical Society
Volume140
Issue number1
DOIs
Publication statusPublished - Jan 10 2018

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Tin
Perovskite
Doping (additives)
Costs and Cost Analysis
Iodides
Conversion efficiency
Cations
Costs
Lead
Positive ions
Perovskite solar cells
perovskite
Air
Molecules
Equipment and Supplies

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Dopant-Free Tetrakis-Triphenylamine Hole Transporting Material for Efficient Tin-Based Perovskite Solar Cells. / Ke, Weijun; Priyanka, Pragya; Vegiraju, Sureshraju; Stoumpos, Constantinos C.; Spanopoulos, Ioannis; Soe, Chan Myae Myae; Marks, Tobin J; Chen, Ming Chou; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 140, No. 1, 10.01.2018, p. 388-393.

Research output: Contribution to journalArticle

Ke, Weijun ; Priyanka, Pragya ; Vegiraju, Sureshraju ; Stoumpos, Constantinos C. ; Spanopoulos, Ioannis ; Soe, Chan Myae Myae ; Marks, Tobin J ; Chen, Ming Chou ; Kanatzidis, Mercouri G. / Dopant-Free Tetrakis-Triphenylamine Hole Transporting Material for Efficient Tin-Based Perovskite Solar Cells. In: Journal of the American Chemical Society. 2018 ; Vol. 140, No. 1. pp. 388-393.
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