Abstract
We have recently shown that square-planar Pt(II) complexes with imine and thiolate ligands are good donor complexes that exhibit electronic absorption bands that can be tuned across the UV-vis-NIR region by varying the ligands and/or adding an organic acceptor. However, in order to be useful for dye-sensitized solar cells, these materials need to be anchored to semiconductor surfaces. We achieve this by either the conventional approach in which carboxylated imines are used (e.g., dcbpy = 4,4′-bypyridine(COOH)2 or cttrpy = 4-[2,2′;6′,2″]-terpyridin-4′-yl-C6H4COOH) or by using nitrile organic acceptors such as TCNQ, which can anchor via their cyano groups. We demonstrated that both approaches lead to dyes that can permanently adsorb to semiconductor surfaces and give the same electronic absorption features as those in solution. Details of our spectral, electrochemical, and solar cell results for such dyes using a variety of ligands and d8 metal centers will be presented.
| Original language | English |
|---|---|
| Title of host publication | ACS National Meeting Book of Abstracts |
| Publication status | Published - 2007 |
| Event | 234th ACS National Meeting - Boston, MA, United States Duration: Aug 19 2007 → Aug 23 2007 |
Other
| Other | 234th ACS National Meeting |
|---|---|
| Country | United States |
| City | Boston, MA |
| Period | 8/19/07 → 8/23/07 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Dye-sensitized solar cells based on square-planar d8 donor complexes without and with organic acceptors. / Chen, Wei Hsuan; Hudson, Joshua M.; Katz, Jordan; Lewis, Nathan S; Omary, Mohammad A.
ACS National Meeting Book of Abstracts. 2007.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Dye-sensitized solar cells based on square-planar d8 donor complexes without and with organic acceptors
AU - Chen, Wei Hsuan
AU - Hudson, Joshua M.
AU - Katz, Jordan
AU - Lewis, Nathan S
AU - Omary, Mohammad A.
PY - 2007
Y1 - 2007
N2 - We have recently shown that square-planar Pt(II) complexes with imine and thiolate ligands are good donor complexes that exhibit electronic absorption bands that can be tuned across the UV-vis-NIR region by varying the ligands and/or adding an organic acceptor. However, in order to be useful for dye-sensitized solar cells, these materials need to be anchored to semiconductor surfaces. We achieve this by either the conventional approach in which carboxylated imines are used (e.g., dcbpy = 4,4′-bypyridine(COOH)2 or cttrpy = 4-[2,2′;6′,2″]-terpyridin-4′-yl-C6H4COOH) or by using nitrile organic acceptors such as TCNQ, which can anchor via their cyano groups. We demonstrated that both approaches lead to dyes that can permanently adsorb to semiconductor surfaces and give the same electronic absorption features as those in solution. Details of our spectral, electrochemical, and solar cell results for such dyes using a variety of ligands and d8 metal centers will be presented.
AB - We have recently shown that square-planar Pt(II) complexes with imine and thiolate ligands are good donor complexes that exhibit electronic absorption bands that can be tuned across the UV-vis-NIR region by varying the ligands and/or adding an organic acceptor. However, in order to be useful for dye-sensitized solar cells, these materials need to be anchored to semiconductor surfaces. We achieve this by either the conventional approach in which carboxylated imines are used (e.g., dcbpy = 4,4′-bypyridine(COOH)2 or cttrpy = 4-[2,2′;6′,2″]-terpyridin-4′-yl-C6H4COOH) or by using nitrile organic acceptors such as TCNQ, which can anchor via their cyano groups. We demonstrated that both approaches lead to dyes that can permanently adsorb to semiconductor surfaces and give the same electronic absorption features as those in solution. Details of our spectral, electrochemical, and solar cell results for such dyes using a variety of ligands and d8 metal centers will be presented.
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UR - http://www.scopus.com/inward/citedby.url?scp=37349116296&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:37349116296
SN - 0841269556
SN - 9780841269552
BT - ACS National Meeting Book of Abstracts
ER -