Dynamics and reaction mechanisms of organic ions in the gas phase

Andrew T. Barfknecht, James A. Dodd, Karen E. Salomon, William Tumas, John I. Brauman

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Abstract

Major advances have been made in the measurement and analysis of gas phase ionic organic reactions. The dynamics can be interpreted in terms of statistical reaction rate theory. The activation parameters and rates have been interpreted in terms of Marcus theory. Infrared multiple photon absorption has been used to activate ions which may be intermediates in these ion-molecule reactions. The results provide information about bimolecular dynamics.

Original languageEnglish
Pages (from-to)1809-1818
Number of pages10
JournalPure and Applied Chemistry
Volume56
Issue number12
DOIs
Publication statusPublished - 1984

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ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Barfknecht, A. T., Dodd, J. A., Salomon, K. E., Tumas, W., & Brauman, J. I. (1984). Dynamics and reaction mechanisms of organic ions in the gas phase. Pure and Applied Chemistry, 56(12), 1809-1818. https://doi.org/10.1351/pac198456121809