Dynamics of charge transfer

Rate processes formulated with nonequilibrium Green's functions

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The authors examine the connection between electron transport under bias in a junction and nonadiabatic intramolecular electron transfer (ET). It is shown that under certain assumptions it is possible to define a stationary current that allows the computation of the intramolecular transfer rate using the same formalism that is employed in the description of transport. They show that the nonequilibrium Green's function formalism of quantum transport can be used to calculate the ET rate. The formal connection between electron transport and electron transfer is made, and they work out the simple case of an electronic level coupled to a vibrational mode representing a thermal bath and show that the result is the same as expected from a Fermi golden rule treatment, and in the high-temperature limit yields the Marcus electron transfer theory. The usefulness of this alternative formulation of rates is discussed.

Original languageEnglish
Article number161103
JournalJournal of Chemical Physics
Volume126
Issue number16
DOIs
Publication statusPublished - 2007

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Green's function
Charge transfer
electron transfer
Green's functions
charge transfer
Electrons
formalism
electronic levels
baths
vibration mode
electrons
formulations
Temperature
Electron Transport

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Dynamics of charge transfer : Rate processes formulated with nonequilibrium Green's functions. / Yeganeh, Sina; Ratner, Mark A; Mujica, Vladimiro.

In: Journal of Chemical Physics, Vol. 126, No. 16, 161103, 2007.

Research output: Contribution to journalArticle

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