Effect of dimensionality on the photocatalytic behavior of carbon-titania nanosheet composites

Charge transfer at nanomaterial interfaces

Yu Teng Liang, Baiju K. Vijayan, Olga Lyandres, Kimberly A. Gray, Mark C Hersam

Research output: Contribution to journalArticle

117 Citations (Scopus)

Abstract

Due to their unique optoelectronic structure and large specific surface area, carbon nanomaterials have been integrated with titania to enhance photocatalysis. In particular, recent work has shown that nanocomposite photocatalytic performance can be improved by minimizing the covalent defect density of the carbon component. Herein, carbon nanotube-titania nanosheet and graphene-titania nanosheet composites with low carbon defect densities are compared to investigate the role of carbon nanomaterial dimensionality on photocatalytic response. The resulting 2D-2D graphene-titania nanosheet composites yield superior electronic coupling compared to 1D-2D carbon nanotube-titania nanosheet composites, leading to greater enhancement factors for CO2 photoreduction under ultraviolet irradiation. On the other hand, 1D carbon nanotubes are shown to be more effective titania photosensitizers, leading to greater photoactivity enhancement factors under visible illumination. Overall, this work suggests that carbon nanomaterial dimensionality is a key factor in determining the spectral response and reaction specificity of carbon-titania nanosheet composite photocatalysts.

Original languageEnglish
Pages (from-to)1760-1765
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume3
Issue number13
DOIs
Publication statusPublished - Jul 5 2012

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Nanosheets
Nanostructured materials
Charge transfer
Carbon
titanium
Titanium
charge transfer
composite materials
carbon
Composite materials
Carbon Nanotubes
Carbon nanotubes
Graphite
Defect density
carbon nanotubes
Graphene
graphene
Photosensitizing Agents
Photosensitizers
Photocatalysis

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Effect of dimensionality on the photocatalytic behavior of carbon-titania nanosheet composites : Charge transfer at nanomaterial interfaces. / Liang, Yu Teng; Vijayan, Baiju K.; Lyandres, Olga; Gray, Kimberly A.; Hersam, Mark C.

In: Journal of Physical Chemistry Letters, Vol. 3, No. 13, 05.07.2012, p. 1760-1765.

Research output: Contribution to journalArticle

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