Abstract
Dye sensitized solar cells have proven a promising approach for solar energy conversion. Optimization of overall efficiency has primarily focused on modification of dye absorption/spectral coverage, electrodes, and electrolyte composition. An important remaining issue is how the absorbed-photon-to-current efficiency (APCE) is effected by the dye-semiconductor electronic coupling. This coupling may be significantly dependent upon the linker, which serves to both anchor the dye to the surface and also mediates the electron transfer. This work focuses on the effect of structural modification of the linker group on charge injection and therefore the solar to electrical energy conversion efficiency. The role of frontier orbital energy levels, orbital geometry, and dye substitution pattern (meso or beta positions) is probed to understand the role of electronic coupling and subsequently any effect on efficiency.
| Original language | English |
|---|---|
| Title of host publication | ACS National Meeting Book of Abstracts |
| Publication status | Published - 2007 |
| Event | 233rd ACS National Meeting - Chicago, IL, United States Duration: Mar 25 2007 → Mar 29 2007 |
Other
| Other | 233rd ACS National Meeting |
|---|---|
| Country | United States |
| City | Chicago, IL |
| Period | 3/25/07 → 3/29/07 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Effect of dye-semiconductor electronic coupling on solar energy conversion efficiency in dye sensitized solar cells. / Ramirez, Ana O.; She, Chunxing; Youm, Kyoung Tae; Lian, Tianquan; Hupp, Joseph T.
ACS National Meeting Book of Abstracts. 2007.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Effect of dye-semiconductor electronic coupling on solar energy conversion efficiency in dye sensitized solar cells
AU - Ramirez, Ana O.
AU - She, Chunxing
AU - Youm, Kyoung Tae
AU - Lian, Tianquan
AU - Hupp, Joseph T
PY - 2007
Y1 - 2007
N2 - Dye sensitized solar cells have proven a promising approach for solar energy conversion. Optimization of overall efficiency has primarily focused on modification of dye absorption/spectral coverage, electrodes, and electrolyte composition. An important remaining issue is how the absorbed-photon-to-current efficiency (APCE) is effected by the dye-semiconductor electronic coupling. This coupling may be significantly dependent upon the linker, which serves to both anchor the dye to the surface and also mediates the electron transfer. This work focuses on the effect of structural modification of the linker group on charge injection and therefore the solar to electrical energy conversion efficiency. The role of frontier orbital energy levels, orbital geometry, and dye substitution pattern (meso or beta positions) is probed to understand the role of electronic coupling and subsequently any effect on efficiency.
AB - Dye sensitized solar cells have proven a promising approach for solar energy conversion. Optimization of overall efficiency has primarily focused on modification of dye absorption/spectral coverage, electrodes, and electrolyte composition. An important remaining issue is how the absorbed-photon-to-current efficiency (APCE) is effected by the dye-semiconductor electronic coupling. This coupling may be significantly dependent upon the linker, which serves to both anchor the dye to the surface and also mediates the electron transfer. This work focuses on the effect of structural modification of the linker group on charge injection and therefore the solar to electrical energy conversion efficiency. The role of frontier orbital energy levels, orbital geometry, and dye substitution pattern (meso or beta positions) is probed to understand the role of electronic coupling and subsequently any effect on efficiency.
UR - http://www.scopus.com/inward/record.url?scp=37349079206&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37349079206&partnerID=8YFLogxK
M3 - Conference contribution
SN - 084127438X
SN - 9780841274389
BT - ACS National Meeting Book of Abstracts
ER -