Abstract
A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N 2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.
| Original language | English |
|---|---|
| Pages (from-to) | 7055-7057 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 63 |
| DOIs | |
| Publication status | Published - Aug 14 2013 |
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ASJC Scopus subject areas
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Catalysis
- Chemistry(all)
Cite this
Effect of ligand geometry on selective gas-adsorption : The case of a microporous cadmium metal organic framework with a V-shaped linker. / Plonka, Anna M.; Banerjee, Debasis; Woerner, William R.; Zhang, Zhijuan; Li, Jing; Parise, John B.
In: Chemical Communications, Vol. 49, No. 63, 14.08.2013, p. 7055-7057.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Effect of ligand geometry on selective gas-adsorption
T2 - The case of a microporous cadmium metal organic framework with a V-shaped linker
AU - Plonka, Anna M.
AU - Banerjee, Debasis
AU - Woerner, William R.
AU - Zhang, Zhijuan
AU - Li, Jing
AU - Parise, John B.
PY - 2013/8/14
Y1 - 2013/8/14
N2 - A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N 2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.
AB - A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N 2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.
UR - http://www.scopus.com/inward/record.url?scp=84882282058&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84882282058&partnerID=8YFLogxK
U2 - 10.1039/c3cc43299h
DO - 10.1039/c3cc43299h
M3 - Article
C2 - 23811783
AN - SCOPUS:84882282058
VL - 49
SP - 7055
EP - 7057
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 63
ER -