Abstract
A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.
| Original language | English |
|---|---|
| Pages (from-to) | 7055-7057 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 63 |
| DOIs | |
| Publication status | Published - Jul 11 2013 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Fingerprint Dive into the research topics of 'Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker'. Together they form a unique fingerprint.
Cite this
Plonka, A. M., Banerjee, D., Woerner, W. R., Zhang, Z., Li, J., & Parise, J. B. (2013). Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker. Chemical Communications, 49(63), 7055-7057. https://doi.org/10.1039/c3cc43299h