Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka; Debasis Banerjee; William R. Woerner; Zhijuan Zhang; Jing Li; John B. Parise

doi:10.1039/c3cc43299h

Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka, Debasis Banerjee, William R. Woerner, Zhijuan Zhang, Jing Li, John B. Parise

Rutgers University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO₂ over N₂. The selectivity is attributed to CO₂ interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

Original language	English
Pages (from-to)	7055-7057
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	63
DOIs	https://doi.org/10.1039/c3cc43299h
Publication status	Published - Jul 11 2013

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c3cc43299h

Fingerprint Dive into the research topics of 'Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker'. Together they form a unique fingerprint.

Cite this

Effect of ligand geometry on selective gas-adsorption : The case of a microporous cadmium metal organic framework with a V-shaped linker. / Plonka, Anna M.; Banerjee, Debasis; Woerner, William R.; Zhang, Zhijuan; Li, Jing; Parise, John B.

In: Chemical Communications, Vol. 49, No. 63, 11.07.2013, p. 7055-7057.

Research output: Contribution to journal › Article › peer-review

@article{c1df9817ed1f4156842095b6b9d2e043,

title = "Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker",

abstract = "A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.",

author = "Plonka, {Anna M.} and Debasis Banerjee and Woerner, {William R.} and Zhijuan Zhang and Jing Li and Parise, {John B.}",

year = "2013",

month = jul,

day = "11",

doi = "10.1039/c3cc43299h",

language = "English",

volume = "49",

pages = "7055--7057",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "63",

}

TY - JOUR

T1 - Effect of ligand geometry on selective gas-adsorption

T2 - The case of a microporous cadmium metal organic framework with a V-shaped linker

AU - Plonka, Anna M.

AU - Banerjee, Debasis

AU - Woerner, William R.

AU - Zhang, Zhijuan

AU - Li, Jing

AU - Parise, John B.

PY - 2013/7/11

Y1 - 2013/7/11

N2 - A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

AB - A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

UR - http://www.scopus.com/inward/record.url?scp=84882282058&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84882282058&partnerID=8YFLogxK

U2 - 10.1039/c3cc43299h

DO - 10.1039/c3cc43299h

M3 - Article

C2 - 23811783

AN - SCOPUS:84882282058

VL - 49

SP - 7055

EP - 7057

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 63

ER -

Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this