Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka; Debasis Banerjee; William R. Woerner; Zhijuan Zhang; Jing Li; John B. Parise

doi:10.1039/c3cc43299h

Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka, Debasis Banerjee, William R. Woerner, Zhijuan Zhang, Jing Li, John B. Parise

Rutgers University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO₂ over N₂. The selectivity is attributed to CO₂ interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

Original language	English
Pages (from-to)	7055-7057
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	63
DOIs	https://doi.org/10.1039/c3cc43299h
Publication status	Published - Jul 11 2013

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Effect of ligand geometry on selective gas-adsorption : The case of a microporous cadmium metal organic framework with a V-shaped linker. / Plonka, Anna M.; Banerjee, Debasis; Woerner, William R.; Zhang, Zhijuan; Li, Jing; Parise, John B.

In: Chemical Communications, Vol. 49, No. 63, 11.07.2013, p. 7055-7057.

Research output: Contribution to journal › Article › peer-review

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