Effect of ligand geometry on selective gas-adsorption

The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka, Debasis Banerjee, William R. Woerner, Zhijuan Zhang, Jing Li, John B. Parise

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N 2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

Original languageEnglish
Pages (from-to)7055-7057
Number of pages3
JournalChemical Communications
Volume49
Issue number63
DOIs
Publication statusPublished - Aug 14 2013

Fingerprint

Gas adsorption
Cadmium
Metals
Ligands
Geometry

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Effect of ligand geometry on selective gas-adsorption : The case of a microporous cadmium metal organic framework with a V-shaped linker. / Plonka, Anna M.; Banerjee, Debasis; Woerner, William R.; Zhang, Zhijuan; Li, Jing; Parise, John B.

In: Chemical Communications, Vol. 49, No. 63, 14.08.2013, p. 7055-7057.

Research output: Contribution to journalArticle

Plonka, Anna M. ; Banerjee, Debasis ; Woerner, William R. ; Zhang, Zhijuan ; Li, Jing ; Parise, John B. / Effect of ligand geometry on selective gas-adsorption : The case of a microporous cadmium metal organic framework with a V-shaped linker. In: Chemical Communications. 2013 ; Vol. 49, No. 63. pp. 7055-7057.
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