Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka; Debasis Banerjee; William R. Woerner; Zhijuan Zhang; Jing Li; John B. Parise

doi:10.1039/c3cc43299h

Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker

Anna M. Plonka, Debasis Banerjee, William R. Woerner, Zhijuan Zhang, Jing Li, John B. Parise

Rutgers University

Research output: Contribution to journal › Article

30 Citations (Scopus)

Abstract

A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO₂ over N ₂. The selectivity is attributed to CO₂ interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

Original language	English
Pages (from-to)	7055-7057
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	63
DOIs	https://doi.org/10.1039/c3cc43299h
Publication status	Published - Aug 14 2013

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Plonka, A. M., Banerjee, D., Woerner, W. R., Zhang, Z., Li, J., & Parise, J. B. (2013). Effect of ligand geometry on selective gas-adsorption: The case of a microporous cadmium metal organic framework with a V-shaped linker. Chemical Communications, 49(63), 7055-7057. https://doi.org/10.1039/c3cc43299h

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Access to Document

10.1039/c3cc43299h