Abstract
Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (VO ⋅⋅) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce0.9Gd0.1O2-δ, δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.
| Original language | English |
|---|---|
| Pages (from-to) | 53-60 |
| Number of pages | 8 |
| Journal | Acta Materialia |
| Volume | 174 |
| DOIs | |
| Publication status | Published - Aug 1 2019 |
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Keywords
- Electrostriction
- Gadolinium-doped ceria
- Sintering
- Vacancies
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Polymers and Plastics
- Metals and Alloys
Cite this
Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties. / Kabir, Ahsanul; Santucci, Simone; Van Nong, Ngo; Varenik, Maxim; Lubomirsky, Igor; Nigon, Robin; Muralt, Paul; Esposito, Vincenzo.
In: Acta Materialia, Vol. 174, 01.08.2019, p. 53-60.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties
AU - Kabir, Ahsanul
AU - Santucci, Simone
AU - Van Nong, Ngo
AU - Varenik, Maxim
AU - Lubomirsky, Igor
AU - Nigon, Robin
AU - Muralt, Paul
AU - Esposito, Vincenzo
PY - 2019/8/1
Y1 - 2019/8/1
N2 - Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (VO ⋅⋅) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce0.9Gd0.1O2-δ, δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.
AB - Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (VO ⋅⋅) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce0.9Gd0.1O2-δ, δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.
KW - Electrostriction
KW - Gadolinium-doped ceria
KW - Sintering
KW - Vacancies
UR - http://www.scopus.com/inward/record.url?scp=85066254488&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85066254488&partnerID=8YFLogxK
U2 - 10.1016/j.actamat.2019.05.009
DO - 10.1016/j.actamat.2019.05.009
M3 - Article
VL - 174
SP - 53
EP - 60
JO - Acta Materialia
JF - Acta Materialia
SN - 1359-6454
ER -