Effect of temperature on hydrogen and carbon dioxide adsorption hysteresis in an ultramicroporous MOF

Haohan Wu, Charles G. Thibault, Hao Wang, Katie A. Cychosz, Matthias Thommes, Jing Li

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Different types of hysteresis commonly observed in gas adsorption isotherms of metal-organic frameworks (MOFs) and possible reasons are discussed. The temperature effect of hydrogen (H2) and carbon dioxide (CO2) adsorption/desorption hysteresis in an ultramicroporous MOF and a method to obtain accurate isosteric heats of adsorption in small-pore adsorbent materials are presented.

Original languageEnglish
Pages (from-to)186-189
Number of pages4
JournalMicroporous and Mesoporous Materials
Volume219
DOIs
Publication statusPublished - Jan 1 2016

Fingerprint

dioxides
Carbon Dioxide
Hysteresis
carbon dioxide
Hydrogen
Carbon dioxide
Metals
hysteresis
Adsorption
Gas adsorption
adsorption
hydrogen
Adsorption isotherms
metals
Thermal effects
Adsorbents
Desorption
adsorbents
Temperature
temperature

Keywords

  • Carbon dioxide adsorption
  • Hydrogen adsorption
  • Structural phase transition
  • Temperature-dependent hysteresis
  • Ultramicroporous MOF

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Effect of temperature on hydrogen and carbon dioxide adsorption hysteresis in an ultramicroporous MOF. / Wu, Haohan; Thibault, Charles G.; Wang, Hao; Cychosz, Katie A.; Thommes, Matthias; Li, Jing.

In: Microporous and Mesoporous Materials, Vol. 219, 01.01.2016, p. 186-189.

Research output: Contribution to journalArticle

Wu, Haohan ; Thibault, Charles G. ; Wang, Hao ; Cychosz, Katie A. ; Thommes, Matthias ; Li, Jing. / Effect of temperature on hydrogen and carbon dioxide adsorption hysteresis in an ultramicroporous MOF. In: Microporous and Mesoporous Materials. 2016 ; Vol. 219. pp. 186-189.
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