Effect of temperature on hydrogen and carbon dioxide adsorption hysteresis in an ultramicroporous MOF

Haohan Wu, Charles G. Thibault, Hao Wang, Katie A. Cychosz, Matthias Thommes, Jing Li

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Different types of hysteresis commonly observed in gas adsorption isotherms of metal-organic frameworks (MOFs) and possible reasons are discussed. The temperature effect of hydrogen (H2) and carbon dioxide (CO2) adsorption/desorption hysteresis in an ultramicroporous MOF and a method to obtain accurate isosteric heats of adsorption in small-pore adsorbent materials are presented.

Original languageEnglish
Pages (from-to)186-189
Number of pages4
JournalMicroporous and Mesoporous Materials
Volume219
DOIs
Publication statusPublished - Jan 1 2016

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Keywords

  • Carbon dioxide adsorption
  • Hydrogen adsorption
  • Structural phase transition
  • Temperature-dependent hysteresis
  • Ultramicroporous MOF

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

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