Effective medium theory of dna-linked gold nanoparticle aggregates: Effect of aggregate shape

Anne A. Lazarides, K. Lance Kelly, George C. Schatz

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We present a dynamical effective medium theory (EMT) of the dielectric properties of nanoparticle aggregates formed from DNA-linked gold nanoparticles. Experimental measurements show that such aggregates have reduced UV extinction and plasmon bands that are considerably red-shifted and broadened relative to the plasmon absorption feature observed in spectra of dispersed colloid. The EMT, which can be used to reproduce the observed spectral changes, is tested by comparing aggregate spectra calculated using the EMT dielectric function with spectra from explicit coupled particle calculations, and good agreement is found. The EMT dielectric function is used as well in discrete dipole calculations to calculate extinction spectra for a variety of aggregate shapes not amenable to analytic solution, and the sensitivity of the spectra to aggregate shape is examined. We find that the spectra are only weakly sensitive to aggregate shape, and conclude that, when calculating extinction of the DNA-linked aggregates fo r comparison with experiment, spherical shapes can be assumed.

Original languageEnglish
Pages (from-to)C651-C6510
JournalMaterials Research Society Symposium - Proceedings
Volume635
DOIs
Publication statusPublished - 2001

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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