Abstract
Basic difference: The importance of a pendent base in promoting proton-coupled electron-transfer reactions with low activation barriers has been discussed for H + reduction or H 2 oxidation in acetonitrile. Investigation of the interaction between a base positioned in the second coordination sphere of a complex and a water ligand in water oxidation reactions using geometric isomers of [Ru(tpy)(pynap)(OH 2)] 2+ (see picture) gave intriguing results.
| Original language | English |
|---|---|
| Pages (from-to) | 12600-12604 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 50 |
| Issue number | 52 |
| DOIs | |
| Publication status | Published - Dec 23 2011 |
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Keywords
- electron transfer
- isomers
- proton reduction
- ruthenium
- water oxidation
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Effects of a proximal base on water oxidation and proton reduction catalyzed by geometric isomers of [Ru(tpy)(pynap)(OH 2)] 2+ . / Boyer, Julie L.; Polyansky, Dmitry; Szalda, David J.; Zong, Ruifa; Thummel, Randolph P.; Fujita, Etsuko.
In: Angewandte Chemie - International Edition, Vol. 50, No. 52, 23.12.2011, p. 12600-12604.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Effects of a proximal base on water oxidation and proton reduction catalyzed by geometric isomers of [Ru(tpy)(pynap)(OH 2)] 2+
AU - Boyer, Julie L.
AU - Polyansky, Dmitry
AU - Szalda, David J.
AU - Zong, Ruifa
AU - Thummel, Randolph P.
AU - Fujita, Etsuko
PY - 2011/12/23
Y1 - 2011/12/23
N2 - Basic difference: The importance of a pendent base in promoting proton-coupled electron-transfer reactions with low activation barriers has been discussed for H + reduction or H 2 oxidation in acetonitrile. Investigation of the interaction between a base positioned in the second coordination sphere of a complex and a water ligand in water oxidation reactions using geometric isomers of [Ru(tpy)(pynap)(OH 2)] 2+ (see picture) gave intriguing results.
AB - Basic difference: The importance of a pendent base in promoting proton-coupled electron-transfer reactions with low activation barriers has been discussed for H + reduction or H 2 oxidation in acetonitrile. Investigation of the interaction between a base positioned in the second coordination sphere of a complex and a water ligand in water oxidation reactions using geometric isomers of [Ru(tpy)(pynap)(OH 2)] 2+ (see picture) gave intriguing results.
KW - electron transfer
KW - isomers
KW - proton reduction
KW - ruthenium
KW - water oxidation
UR - http://www.scopus.com/inward/record.url?scp=84255188061&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84255188061&partnerID=8YFLogxK
U2 - 10.1002/anie.201102648
DO - 10.1002/anie.201102648
M3 - Article
C2 - 22057468
AN - SCOPUS:84255188061
VL - 50
SP - 12600
EP - 12604
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 52
ER -