Effects of anharmonicity and electronic coupling on photoinduced electron transfer in mixed valence compounds

Daren M. Lockwood, Mark A Ratner, Ronnie Kosloff

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

A semigroup model of electron transfer dynamics in mixed valence compounds was developed. The resultant model elucidates the effects of anharmonicity in inner sphere nuclear modes, as well as the dependence of the electronic dynamics on the nature of the electronic coupling. Including the anharmonicity in inner sphere vibrations resulted to a very small increase in the ET rate.

Original languageEnglish
Pages (from-to)10125-10132
Number of pages8
JournalJournal of Chemical Physics
Volume117
Issue number22
DOIs
Publication statusPublished - Dec 8 2002

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electron transfer
valence
Electrons
electronics
vibration

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Effects of anharmonicity and electronic coupling on photoinduced electron transfer in mixed valence compounds. / Lockwood, Daren M.; Ratner, Mark A; Kosloff, Ronnie.

In: Journal of Chemical Physics, Vol. 117, No. 22, 08.12.2002, p. 10125-10132.

Research output: Contribution to journalArticle

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