Efficient bifunctional nanocatalysts by simple postgrafting of spatially isolated catalytic groups on mesoporous materials

Krishna K. Sharma; Tewodros Asefa

doi:10.1002/anie.200604570

Efficient bifunctional nanocatalysts by simple postgrafting of spatially isolated catalytic groups on mesoporous materials

Krishna K. Sharma, Tewodros Asefa

Rutgers University

Research output: Contribution to journal › Article › peer-review

176 Citations (Scopus)

Abstract

(Chemical Equation Presented) Hard graft pays off for Henry: An efficient acid-base bifunctional mesoporous catalyst was prepared by one-step post-synthesis grafting of aminoorganoalkoxysilane groups on mesoporous silica (see picture). The catalyst led to yields of over 99 % in the Henry reaction (nitroaldol condensation) of p-hydroxybenzaldehyde and nitromethane to form nitrostyrene.

Original language	English
Pages (from-to)	2879-2882
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	16
DOIs	https://doi.org/10.1002/anie.200604570
Publication status	Published - Jul 2 2007

Keywords

Bifunctional catalysts
Henry reaction
Heterogeneous catalysis
Mesoporous materials
Nanostructures

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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