Efficient H2 generation from formic acid using azole complexes in water

Yuichi Manaka, Wan Hui Wang, Yuki Suna, Hide Kambayashi, James Muckerman, Etsuko Fujita, Yuichiro Himeda

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H2-CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34 000 h-1 at 80 °C.

Original languageEnglish
Pages (from-to)34-37
Number of pages4
JournalCatalysis Science and Technology
Volume4
Issue number1
DOIs
Publication statusPublished - Jan 2014

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formic acid
Iridium
Azoles
Formic acid
Dehydrogenation
Water

ASJC Scopus subject areas

  • Catalysis

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Efficient H2 generation from formic acid using azole complexes in water. / Manaka, Yuichi; Wang, Wan Hui; Suna, Yuki; Kambayashi, Hide; Muckerman, James; Fujita, Etsuko; Himeda, Yuichiro.

In: Catalysis Science and Technology, Vol. 4, No. 1, 01.2014, p. 34-37.

Research output: Contribution to journalArticle

Manaka, Yuichi ; Wang, Wan Hui ; Suna, Yuki ; Kambayashi, Hide ; Muckerman, James ; Fujita, Etsuko ; Himeda, Yuichiro. / Efficient H2 generation from formic acid using azole complexes in water. In: Catalysis Science and Technology. 2014 ; Vol. 4, No. 1. pp. 34-37.
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