Efficient H2 generation from formic acid using azole complexes in water

Yuichi Manaka; Wan Hui Wang; Yuki Suna; Hide Kambayashi; James T. Muckerman; Etsuko Fujita; Yuichiro Himeda

doi:10.1039/c3cy00830d

Efficient H₂ generation from formic acid using azole complexes in water

Yuichi Manaka, Wan Hui Wang, Yuki Suna, Hide Kambayashi, James T. Muckerman, Etsuko Fujita, Yuichiro Himeda

Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H₂-CO₂ (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34 000 h^-1 at 80 °C.

Original language	English
Pages (from-to)	34-37
Number of pages	4
Journal	Catalysis Science and Technology
Volume	4
Issue number	1
DOIs	https://doi.org/10.1039/c3cy00830d
Publication status	Published - Jan 1 2014

ASJC Scopus subject areas

Catalysis

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title = "Efficient H2 generation from formic acid using azole complexes in water",

abstract = "Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H2-CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34 000 h-1 at 80 °C.",

author = "Yuichi Manaka and Wang, {Wan Hui} and Yuki Suna and Hide Kambayashi and Muckerman, {James T.} and Etsuko Fujita and Yuichiro Himeda",

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AU - Fujita, Etsuko

AU - Himeda, Yuichiro

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AB - Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H2-CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34 000 h-1 at 80 °C.

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