Efficient hydrogen liberation from formic acid catalyzed by a well-defined iron pincer complex under mild conditions

Thomas Zell, Burkhard Butschke, Yehoshoa Ben-David, David Milstein

Research output: Contribution to journalArticle

137 Citations (Scopus)

Abstract

Hydrogen liberation: An attractive approach to reversible hydrogen storage applications is based on the decomposition of formic acid. The efficient and selective hydrogen liberation from formic acid is catalyzed by an iron pincer complex in the presence of trialkylamine (see scheme). Turnover frequencies up to 836 h-1 and turnover numbers up to 100 000 were achieved at 40°C. A mechanism including well-defined intermediates is suggested on the basis of experimental and computational data.

Original languageEnglish
Pages (from-to)8068-8072
Number of pages5
JournalChemistry - A European Journal
Volume19
Issue number25
DOIs
Publication statusPublished - Jun 17 2013

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formic acid
Formic acid
Hydrogen
Iron
Hydrogen storage
Decomposition

Keywords

  • formic acid
  • homogenous catalysis
  • hydrogen generation
  • iron
  • pincer ligands

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Efficient hydrogen liberation from formic acid catalyzed by a well-defined iron pincer complex under mild conditions. / Zell, Thomas; Butschke, Burkhard; Ben-David, Yehoshoa; Milstein, David.

In: Chemistry - A European Journal, Vol. 19, No. 25, 17.06.2013, p. 8068-8072.

Research output: Contribution to journalArticle

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