Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols

Ekambaram Balaraman; Eran Fogler; David Milstein

doi:10.1039/c1cc15778g

Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols

Ekambaram Balaraman, Eran Fogler, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

99 Citations (Scopus)

Abstract

The unprecedented homogeneous hydrogenation of cyclic di-esters, in particular biomass-derived glycolide and lactide, to the corresponding 1,2-diols is catalyzed by Ru(ii) PNN (1) and Ru(ii) CNN (2) pincer complexes under mild hydrogen pressure and (in the case of 1) neutral conditions. No racemization was observed when a chiral di-ester was used.

Original language	English
Pages (from-to)	1111-1113
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	8
DOIs	https://doi.org/10.1039/c1cc15778g
Publication status	Published - Jan 4 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c1cc15778g

Fingerprint Dive into the research topics of 'Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols'. Together they form a unique fingerprint.

Cite this

@article{ef51991e5bcb47868de914e4f370b333,

title = "Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols",

abstract = "The unprecedented homogeneous hydrogenation of cyclic di-esters, in particular biomass-derived glycolide and lactide, to the corresponding 1,2-diols is catalyzed by Ru(ii) PNN (1) and Ru(ii) CNN (2) pincer complexes under mild hydrogen pressure and (in the case of 1) neutral conditions. No racemization was observed when a chiral di-ester was used.",

author = "Ekambaram Balaraman and Eran Fogler and David Milstein",

year = "2012",

month = jan,

day = "4",

doi = "10.1039/c1cc15778g",

language = "English",

volume = "48",

pages = "1111--1113",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols

AU - Balaraman, Ekambaram

AU - Fogler, Eran

AU - Milstein, David

PY - 2012/1/4

Y1 - 2012/1/4

N2 - The unprecedented homogeneous hydrogenation of cyclic di-esters, in particular biomass-derived glycolide and lactide, to the corresponding 1,2-diols is catalyzed by Ru(ii) PNN (1) and Ru(ii) CNN (2) pincer complexes under mild hydrogen pressure and (in the case of 1) neutral conditions. No racemization was observed when a chiral di-ester was used.

AB - The unprecedented homogeneous hydrogenation of cyclic di-esters, in particular biomass-derived glycolide and lactide, to the corresponding 1,2-diols is catalyzed by Ru(ii) PNN (1) and Ru(ii) CNN (2) pincer complexes under mild hydrogen pressure and (in the case of 1) neutral conditions. No racemization was observed when a chiral di-ester was used.

UR - http://www.scopus.com/inward/record.url?scp=84855612962&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84855612962&partnerID=8YFLogxK

U2 - 10.1039/c1cc15778g

DO - 10.1039/c1cc15778g

M3 - Article

C2 - 22038098

AN - SCOPUS:84855612962

VL - 48

SP - 1111

EP - 1113

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 8

ER -

Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this