Abstract
The electrical conductivity and thermopower of Mn//3O//4 were measured in the temperature range 920 degree to 1530 degree C. Electrical conduction in cubic Mn//3O//4 is explained by the small polaron hopping of electron holes between Mn**4** plus and Mn**3** plus on octahedral sites. The concentrations of Mn**4** plus and Mn**3** plus are governed by the disproportionation equilibrium 2Mn//o//c//t**3** plus reversible reaction Mn//o//c//t**4** plus plus Mn//o//c//t**2** plus . This model also explains the electrical behavior of NiMn//2O//4 and CuMn//2O//4.
| Original language | English |
|---|---|
| Pages (from-to) | 379-385 |
| Number of pages | 7 |
| Journal | Journal of the American Ceramic Society |
| Volume | 71 |
| Issue number | 5 |
| Publication status | Published - May 1988 |
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ASJC Scopus subject areas
- Ceramics and Composites
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ELECTRICAL PROPERTIES AND CATION VALENCIES IN Mn//3O//4. / Dorris, S. E.; Mason, Thomas O.
In: Journal of the American Ceramic Society, Vol. 71, No. 5, 05.1988, p. 379-385.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - ELECTRICAL PROPERTIES AND CATION VALENCIES IN Mn//3O//4.
AU - Dorris, S. E.
AU - Mason, Thomas O
PY - 1988/5
Y1 - 1988/5
N2 - The electrical conductivity and thermopower of Mn//3O//4 were measured in the temperature range 920 degree to 1530 degree C. Electrical conduction in cubic Mn//3O//4 is explained by the small polaron hopping of electron holes between Mn**4** plus and Mn**3** plus on octahedral sites. The concentrations of Mn**4** plus and Mn**3** plus are governed by the disproportionation equilibrium 2Mn//o//c//t**3** plus reversible reaction Mn//o//c//t**4** plus plus Mn//o//c//t**2** plus . This model also explains the electrical behavior of NiMn//2O//4 and CuMn//2O//4.
AB - The electrical conductivity and thermopower of Mn//3O//4 were measured in the temperature range 920 degree to 1530 degree C. Electrical conduction in cubic Mn//3O//4 is explained by the small polaron hopping of electron holes between Mn**4** plus and Mn**3** plus on octahedral sites. The concentrations of Mn**4** plus and Mn**3** plus are governed by the disproportionation equilibrium 2Mn//o//c//t**3** plus reversible reaction Mn//o//c//t**4** plus plus Mn//o//c//t**2** plus . This model also explains the electrical behavior of NiMn//2O//4 and CuMn//2O//4.
UR - http://www.scopus.com/inward/record.url?scp=0024013901&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0024013901&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0024013901
VL - 71
SP - 379
EP - 385
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
SN - 0002-7820
IS - 5
ER -