Abstract
The high-temperature electrical properties (conductivity and thermopower) of the Co//0//. //4Fe//2//. //6O//4-Mn//0//. //4Fe//2//. //6O//4 join were measured in order to determine the cation intersite distribution and establish the conduction mechanism. The cobalt and manganese site occupancies show a nearly linear composition dependence. Trivalent iron occupancies reflect the transition from an octahedral substituent (Co) to a tetrahedral substituent (Mn), but any influence on the iron distribution reaction is minimal.
| Original language | English |
|---|---|
| Pages (from-to) | 213-218 |
| Number of pages | 6 |
| Journal | Journal of the American Ceramic Society |
| Volume | 71 |
| Issue number | 4 |
| Publication status | Published - Apr 1988 |
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ASJC Scopus subject areas
- Ceramics and Composites
Cite this
ELECTRICAL PROPERTIES AND SITE DISTRIBUTION OF CATIONS IN (Mn//yCo//1// minus //y)//0//. //4Fe//2//. //6O//4. / Carter, Daniel C.; Mason, Thomas O.
In: Journal of the American Ceramic Society, Vol. 71, No. 4, 04.1988, p. 213-218.Research output: Contribution to journal › Article
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TY - JOUR
T1 - ELECTRICAL PROPERTIES AND SITE DISTRIBUTION OF CATIONS IN (Mn//yCo//1// minus //y)//0//. //4Fe//2//. //6O//4.
AU - Carter, Daniel C.
AU - Mason, Thomas O
PY - 1988/4
Y1 - 1988/4
N2 - The high-temperature electrical properties (conductivity and thermopower) of the Co//0//. //4Fe//2//. //6O//4-Mn//0//. //4Fe//2//. //6O//4 join were measured in order to determine the cation intersite distribution and establish the conduction mechanism. The cobalt and manganese site occupancies show a nearly linear composition dependence. Trivalent iron occupancies reflect the transition from an octahedral substituent (Co) to a tetrahedral substituent (Mn), but any influence on the iron distribution reaction is minimal.
AB - The high-temperature electrical properties (conductivity and thermopower) of the Co//0//. //4Fe//2//. //6O//4-Mn//0//. //4Fe//2//. //6O//4 join were measured in order to determine the cation intersite distribution and establish the conduction mechanism. The cobalt and manganese site occupancies show a nearly linear composition dependence. Trivalent iron occupancies reflect the transition from an octahedral substituent (Co) to a tetrahedral substituent (Mn), but any influence on the iron distribution reaction is minimal.
UR - http://www.scopus.com/inward/record.url?scp=0023995883&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0023995883&partnerID=8YFLogxK
M3 - Article
VL - 71
SP - 213
EP - 218
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
SN - 0002-7820
IS - 4
ER -