ELECTRICAL PROPERTIES AND SITE DISTRIBUTION OF CATIONS IN (Mn//yCo//1// minus //y)//0//. //4Fe//2//. //6O//4.

Daniel C. Carter; Thomas O Mason

ELECTRICAL PROPERTIES AND SITE DISTRIBUTION OF CATIONS IN (Mn//yCo//1// minus //y)//0//. //4Fe//2//. //6O//4.

Daniel C. Carter, Thomas O Mason

Northwestern University

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

The high-temperature electrical properties (conductivity and thermopower) of the Co//0//. //4Fe//2//. //6O//4-Mn//0//. //4Fe//2//. //6O//4 join were measured in order to determine the cation intersite distribution and establish the conduction mechanism. The cobalt and manganese site occupancies show a nearly linear composition dependence. Trivalent iron occupancies reflect the transition from an octahedral substituent (Co) to a tetrahedral substituent (Mn), but any influence on the iron distribution reaction is minimal.

Original language	English
Pages (from-to)	213-218
Number of pages	6
Journal	Journal of the American Ceramic Society
Volume	71
Issue number	4
Publication status	Published - Apr 1988

ASJC Scopus subject areas

Ceramics and Composites

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title = "ELECTRICAL PROPERTIES AND SITE DISTRIBUTION OF CATIONS IN (Mn//yCo//1// minus //y)//0//. //4Fe//2//. //6O//4.",

abstract = "The high-temperature electrical properties (conductivity and thermopower) of the Co//0//. //4Fe//2//. //6O//4-Mn//0//. //4Fe//2//. //6O//4 join were measured in order to determine the cation intersite distribution and establish the conduction mechanism. The cobalt and manganese site occupancies show a nearly linear composition dependence. Trivalent iron occupancies reflect the transition from an octahedral substituent (Co) to a tetrahedral substituent (Mn), but any influence on the iron distribution reaction is minimal.",

author = "Carter, {Daniel C.} and Mason, {Thomas O}",

year = "1988",

month = apr,

language = "English",

volume = "71",

pages = "213--218",

journal = "Journal of the American Ceramic Society",

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publisher = "Wiley-Blackwell",

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T1 - ELECTRICAL PROPERTIES AND SITE DISTRIBUTION OF CATIONS IN (Mn//yCo//1// minus //y)//0//. //4Fe//2//. //6O//4.

AU - Carter, Daniel C.

AU - Mason, Thomas O

PY - 1988/4

Y1 - 1988/4

N2 - The high-temperature electrical properties (conductivity and thermopower) of the Co//0//. //4Fe//2//. //6O//4-Mn//0//. //4Fe//2//. //6O//4 join were measured in order to determine the cation intersite distribution and establish the conduction mechanism. The cobalt and manganese site occupancies show a nearly linear composition dependence. Trivalent iron occupancies reflect the transition from an octahedral substituent (Co) to a tetrahedral substituent (Mn), but any influence on the iron distribution reaction is minimal.

AB - The high-temperature electrical properties (conductivity and thermopower) of the Co//0//. //4Fe//2//. //6O//4-Mn//0//. //4Fe//2//. //6O//4 join were measured in order to determine the cation intersite distribution and establish the conduction mechanism. The cobalt and manganese site occupancies show a nearly linear composition dependence. Trivalent iron occupancies reflect the transition from an octahedral substituent (Co) to a tetrahedral substituent (Mn), but any influence on the iron distribution reaction is minimal.

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