Electrocatalytic functionalization of alkanes using aqueous platinum salts

Michael S. Freund, Jay A. Labinger, Nathan S Lewis, John E. Bercaw

Research output: Contribution to journal › Article

31 Citations (Scopus)

Abstract

p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO3SC6H4CH2OH, by a system consisting of aqueous PtCl2- 4 as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.

Original languageEnglish
JournalJournal of Molecular Catalysis
Volume87
Issue number1
DOIs
Publication statusPublished - Jan 19 1994

Fingerprint

Paraffins
Platinum
Salts
Electrochemical cells
Acids
Anodes
Alcohols
Chemical activation
Catalysts
Carbon
Oxidation-Reduction

Keywords

  • electrocatalysis
  • hydroxylation
  • platinum
  • selective oxidation

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Electrocatalytic functionalization of alkanes using aqueous platinum salts. / Freund, Michael S.; Labinger, Jay A.; Lewis, Nathan S; Bercaw, John E.

In: Journal of Molecular Catalysis, Vol. 87, No. 1, 19.01.1994.

Research output: Contribution to journal › Article

Freund, MS, Labinger, JA, Lewis, NS & Bercaw, JE 1994, 'Electrocatalytic functionalization of alkanes using aqueous platinum salts', Journal of Molecular Catalysis, vol. 87, no. 1. https://doi.org/10.1016/0304-5102(93)E0230-E
Freund MS, Labinger JA, Lewis NS, Bercaw JE. Electrocatalytic functionalization of alkanes using aqueous platinum salts. Journal of Molecular Catalysis. 1994 Jan 19;87(1). https://doi.org/10.1016/0304-5102(93)E0230-E
Freund, Michael S. ; Labinger, Jay A. ; Lewis, Nathan S ; Bercaw, John E. / Electrocatalytic functionalization of alkanes using aqueous platinum salts. In: Journal of Molecular Catalysis. 1994 ; Vol. 87, No. 1.
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