Electrocatalytic functionalization of alkanes using aqueous platinum salts

Michael S. Freund; Jay A. Labinger; Nathan S Lewis; John E. Bercaw

doi:10.1016/0304-5102(93)E0230-E

Electrocatalytic functionalization of alkanes using aqueous platinum salts

Michael S. Freund, Jay A. Labinger, Nathan S Lewis, John E. Bercaw

California Institute of Technology

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO₃SC₆H₄CH₂OH, by a system consisting of aqueous PtCl^2- ₄ as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.

Original language	English
Journal	Journal of Molecular Catalysis
Volume	87
Issue number	1
DOIs	https://doi.org/10.1016/0304-5102(93)E0230-E
Publication status	Published - Jan 19 1994

Keywords

electrocatalysis
hydroxylation
platinum
selective oxidation

ASJC Scopus subject areas

Engineering(all)

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10.1016/0304-5102(93)E0230-E

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title = "Electrocatalytic functionalization of alkanes using aqueous platinum salts",

abstract = "p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO3SC6H4CH2OH, by a system consisting of aqueous PtCl2- 4 as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.",

keywords = "electrocatalysis, hydroxylation, platinum, selective oxidation",

author = "Freund, {Michael S.} and Labinger, {Jay A.} and Lewis, {Nathan S} and Bercaw, {John E.}",

year = "1994",

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journal = "Journal of Molecular Catalysis",

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T1 - Electrocatalytic functionalization of alkanes using aqueous platinum salts

AU - Freund, Michael S.

AU - Labinger, Jay A.

AU - Lewis, Nathan S

AU - Bercaw, John E.

PY - 1994/1/19

Y1 - 1994/1/19

N2 - p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO3SC6H4CH2OH, by a system consisting of aqueous PtCl2- 4 as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.

AB - p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO3SC6H4CH2OH, by a system consisting of aqueous PtCl2- 4 as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.

KW - electrocatalysis

KW - hydroxylation

KW - platinum

KW - selective oxidation

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JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

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