Electrocatalytic functionalization of alkanes using aqueous platinum salts

Michael S. Freund; Jay A. Labinger; Nathan S Lewis; John E. Bercaw

doi:10.1016/0304-5102(93)E0230-E

Electrocatalytic functionalization of alkanes using aqueous platinum salts

Michael S. Freund, Jay A. Labinger, Nathan S Lewis, John E. Bercaw

California Institute of Technology

Research output: Contribution to journal › Article

35 Citations (Scopus)

Abstract

p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO₃SC₆H₄CH₂OH, by a system consisting of aqueous PtCl^2- ₄ as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.

Original language	English
Journal	Journal of Molecular Catalysis
Volume	87
Issue number	1
DOIs	https://doi.org/10.1016/0304-5102(93)E0230-E
Publication status	Published - Jan 19 1994

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Keywords

electrocatalysis
hydroxylation
platinum
selective oxidation

ASJC Scopus subject areas

Engineering(all)

Cite this

Freund, M. S., Labinger, J. A., Lewis, N. S., & Bercaw, J. E. (1994). Electrocatalytic functionalization of alkanes using aqueous platinum salts. Journal of Molecular Catalysis, 87(1). https://doi.org/10.1016/0304-5102(93)E0230-E

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abstract = "p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO3SC6H4CH2OH, by a system consisting of aqueous PtCl2- 4 as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.",

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AU - Bercaw, John E.

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N2 - p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO3SC6H4CH2OH, by a system consisting of aqueous PtCl2- 4 as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.

AB - p-Toluenesulfonic acid is electrocatalytically hydroxylated to the alcohol,p-HO3SC6H4CH2OH, by a system consisting of aqueous PtCl2- 4 as CH activation catalyst, phosphomolybdic acid as redox mediator, in an electrochemical cell containing a carbon cloth anode.

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KW - hydroxylation

KW - platinum

KW - selective oxidation

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Access to Document

10.1016/0304-5102(93)E0230-E