Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu; Brandi M. Cossairt; Bruce S. Brunschwig; Nathan S. Lewis; Jonas C. Peters

doi:10.1039/b509188h

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu, Brandi M. Cossairt, Bruce S. Brunschwig, Nathan S. Lewis, Jonas C. Peters

California Institute of Technology

Research output: Contribution to journal › Article

224 Citations (Scopus)

Abstract

In the presence of moderately strong acids in CH₃CN, cobalt complexes with BF₂-bridged diglyoxime ligands are active catalysts for the reduction of protons to H₂ at potentials as positive as -0.28 V vs. SCE.

Original language	English
Pages (from-to)	4723-4725
Number of pages	3
Journal	Chemical Communications
Issue number	37
DOIs	https://doi.org/10.1039/b509188h
Publication status	Published - Oct 7 2005

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Hu, X., Cossairt, B. M., Brunschwig, B. S., Lewis, N. S., & Peters, J. C. (2005). Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chemical Communications, (37), 4723-4725. https://doi.org/10.1039/b509188h

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abstract = "In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.",

author = "Xile Hu and Cossairt, {Brandi M.} and Brunschwig, {Bruce S.} and Lewis, {Nathan S.} and Peters, {Jonas C.}",

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