Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu; Brandi M. Cossairt; Bruce S. Brunschwig; Nathan S. Lewis; Jonas C. Peters

doi:10.1039/b509188h

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu, Brandi M. Cossairt, Bruce S. Brunschwig, Nathan S. Lewis, Jonas C. Peters

California Institute of Technology

Research output: Contribution to journal › Article › peer-review

229 Citations (Scopus)

Abstract

In the presence of moderately strong acids in CH₃CN, cobalt complexes with BF₂-bridged diglyoxime ligands are active catalysts for the reduction of protons to H₂ at potentials as positive as -0.28 V vs. SCE.

Original language	English
Pages (from-to)	4723-4725
Number of pages	3
Journal	Chemical Communications
Issue number	37
DOIs	https://doi.org/10.1039/b509188h
Publication status	Published - Oct 7 2005

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes",

abstract = "In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.",

author = "Xile Hu and Cossairt, {Brandi M.} and Brunschwig, {Bruce S.} and Lewis, {Nathan S.} and Peters, {Jonas C.}",

year = "2005",

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doi = "10.1039/b509188h",

language = "English",

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journal = "Chemical Communications",

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T1 - Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

AU - Hu, Xile

AU - Cossairt, Brandi M.

AU - Brunschwig, Bruce S.

AU - Lewis, Nathan S.

AU - Peters, Jonas C.

PY - 2005/10/7

Y1 - 2005/10/7

N2 - In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.

AB - In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.

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DO - 10.1039/b509188h

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 37

ER -

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Abstract

ASJC Scopus subject areas

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