Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu, Brandi M. Cossairt, Bruce S. Brunschwig, Nathan S Lewis, Jonas C. Peters

Research output: Contribution to journalArticle

204 Citations (Scopus)

Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.

Original languageEnglish
Pages (from-to)4723-4725
Number of pages3
JournalChemical Communications
Issue number37
DOIs
Publication statusPublished - Oct 7 2005

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Cobalt
Protons
Hydrogen
Ligands
Catalysts
Acids

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. / Hu, Xile; Cossairt, Brandi M.; Brunschwig, Bruce S.; Lewis, Nathan S; Peters, Jonas C.

In: Chemical Communications, No. 37, 07.10.2005, p. 4723-4725.

Research output: Contribution to journalArticle

Hu, Xile ; Cossairt, Brandi M. ; Brunschwig, Bruce S. ; Lewis, Nathan S ; Peters, Jonas C. / Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. In: Chemical Communications. 2005 ; No. 37. pp. 4723-4725.
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