Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu; Brandi M. Cossairt; Bruce S. Brunschwig; Nathan S. Lewis; Jonas C. Peters

doi:10.1039/b509188h

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu, Brandi M. Cossairt, Bruce S. Brunschwig, Nathan S. Lewis, Jonas C. Peters

California Institute of Technology

Research output: Contribution to journal › Article

213 Citations (Scopus)

Abstract

In the presence of moderately strong acids in CH₃CN, cobalt complexes with BF₂-bridged diglyoxime ligands are active catalysts for the reduction of protons to H₂ at potentials as positive as -0.28 V vs. SCE.

Original language	English
Pages (from-to)	4723-4725
Number of pages	3
Journal	Chemical Communications
Issue number	37
DOIs	https://doi.org/10.1039/b509188h
Publication status	Published - Oct 7 2005

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Hu, X., Cossairt, B. M., Brunschwig, B. S., Lewis, N. S., & Peters, J. C. (2005). Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chemical Communications, (37), 4723-4725. https://doi.org/10.1039/b509188h

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abstract = "In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.",

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Access to Document

10.1039/b509188h