Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

Shixiong Min; Shahid Rasul; Huaifeng Li; David C. Grills; Kazuhiro Takanabe; Lain Jong Li; Kuo Wei Huang

doi:10.1002/cplu.201500474

Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN³-Ru Pincer Complex

Shixiong Min, Shahid Rasul, Huaifeng Li, David C. Grills, Kazuhiro Takanabe, Lain Jong Li, Kuo Wei Huang

Brookhaven National Laboratory

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

A well-defined PN³-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO₂ reduction to CO and HCOOH with negligible formation of H₂ in a H₂O/MeCN mixture. Done in a pince: A PN³-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO₂ reduction to CO and HCOOH in MeCN/H₂O.

Original language	English
Pages (from-to)	166-171
Number of pages	6
Journal	ChemPlusChem
Volume	81
Issue number	2
DOIs	https://doi.org/10.1002/cplu.201500474
Publication status	Published - Feb 1 2016

Keywords

N,P ligands
electrocatalysts
electrochemistry
redox
ruthenium

ASJC Scopus subject areas

Chemistry(all)

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10.1002/cplu.201500474

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Min, S., Rasul, S., Li, H., Grills, D. C., Takanabe, K., Li, L. J., & Huang, K. W. (2016). Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN³-Ru Pincer Complex. ChemPlusChem, 81(2), 166-171. https://doi.org/10.1002/cplu.201500474

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