Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

Shixiong Min, Shahid Rasul, Huaifeng Li, David Grills, Kazuhiro Takanabe, Lain Jong Li, Kuo Wei Huang

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pince: A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.

Original languageEnglish
Pages (from-to)166-171
Number of pages6
JournalChemPlusChem
Volume81
Issue number2
DOIs
Publication statusPublished - Feb 1 2016

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Electrocatalysts
Carbon Monoxide
Carbon Dioxide
Bearings (structural)
Ligands
Oxidation-Reduction

Keywords

  • electrocatalysts
  • electrochemistry
  • N,P ligands
  • redox
  • ruthenium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex. / Min, Shixiong; Rasul, Shahid; Li, Huaifeng; Grills, David; Takanabe, Kazuhiro; Li, Lain Jong; Huang, Kuo Wei.

In: ChemPlusChem, Vol. 81, No. 2, 01.02.2016, p. 166-171.

Research output: Contribution to journal › Article

Min, S, Rasul, S, Li, H, Grills, D, Takanabe, K, Li, LJ & Huang, KW 2016, 'Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex', ChemPlusChem, vol. 81, no. 2, pp. 166-171. https://doi.org/10.1002/cplu.201500474
Min S, Rasul S, Li H, Grills D, Takanabe K, Li LJ et al. Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex. ChemPlusChem. 2016 Feb 1;81(2):166-171. https://doi.org/10.1002/cplu.201500474
Min, Shixiong ; Rasul, Shahid ; Li, Huaifeng ; Grills, David ; Takanabe, Kazuhiro ; Li, Lain Jong ; Huang, Kuo Wei. / Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex. In: ChemPlusChem. 2016 ; Vol. 81, No. 2. pp. 166-171.
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