Abstract
The electrochemical behavior of [MnIII(terpy)(N3)3] (1) (terpy = 2,2′:6′,2″-terpyridine), a structural model of the azide complex of the manganese superoxide dismutase (MnSOD), has been investigated in acetonitrile (CH3CN) solution. In CH3CN containing either 0.1 M tetra-n-butylammonium perchlorate (Bu4NClO4) or tetraethylammonium trifluoroacetate (Et4NCF3CO2) as supporting electrolytes, the cyclic voltammogram of 1 exhibits one quasi-reversible reduction wave at E1/2 = - 0.170 V versus Ag
Original language | English |
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Pages (from-to) | 99-105 |
Number of pages | 7 |
Journal | Journal of Electroanalytical Chemistry |
Volume | 506 |
Issue number | 2 |
DOIs | |
Publication status | Published - Jun 29 2001 |
Keywords
- Azide
- Bridging ligands
- Complex
- Manganese
- Molecular electrochemistry
- Oxo-bridged complexes
ASJC Scopus subject areas
- Chemical Engineering(all)
- Analytical Chemistry
- Electrochemistry